Multi-functional nanoscale ZrO2 catalysts for sustainable water treatment

This study aimed to synthesize highly reactive ZrO2 nanoparticles using a straightforward sol-gel method for addressing water contamination from hazardous metal ions and organic dyes. Structural and photocatalytic properties were assessed using X-ray diffraction (XRD), Fourier transmission Infrared...

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Published in:Materials Chemistry and Physics
Main Author: Geetha M.; Vashisht N.B.; Thanvir S.; Roslan N.C.; Mohamedzain T.H.; Alfarwati S.; Al-Lohedan H.; Rajabathar J.R.; Zaidi S.A.; Sadasivuni K.K.
Format: Article
Language:English
Published: Elsevier Ltd 2024
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85185839924&doi=10.1016%2fj.matchemphys.2024.129096&partnerID=40&md5=675d16db24907c82eb0978adc545fa2a
id 2-s2.0-85185839924
spelling 2-s2.0-85185839924
Geetha M.; Vashisht N.B.; Thanvir S.; Roslan N.C.; Mohamedzain T.H.; Alfarwati S.; Al-Lohedan H.; Rajabathar J.R.; Zaidi S.A.; Sadasivuni K.K.
Multi-functional nanoscale ZrO2 catalysts for sustainable water treatment
2024
Materials Chemistry and Physics
316

10.1016/j.matchemphys.2024.129096
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85185839924&doi=10.1016%2fj.matchemphys.2024.129096&partnerID=40&md5=675d16db24907c82eb0978adc545fa2a
This study aimed to synthesize highly reactive ZrO2 nanoparticles using a straightforward sol-gel method for addressing water contamination from hazardous metal ions and organic dyes. Structural and photocatalytic properties were assessed using X-ray diffraction (XRD), Fourier transmission Infrared spectroscopy (FTIR), Transmission electron microscopy (TEM), and UV–visible absorption spectroscopy. XRD analysis confirmed the tetragonal crystal structure of ZrO2. Photodegradation experiments using Eriochrome Black T (EBT) as a model dye revealed nearly 99% degradation under natural sunlight. Investigations into catalyst loading, dye concentration, pH, and irradiation source were conducted. Preliminary tests demonstrated the adsorbent's efficacy in removing Ca2+ ions. Further process optimizations could significantly enhance the potential of this innovative adsorbent for extracting metal ions from complex effluents. © 2024 The Authors
Elsevier Ltd
2540584
English
Article
All Open Access
author Geetha M.; Vashisht N.B.; Thanvir S.; Roslan N.C.; Mohamedzain T.H.; Alfarwati S.; Al-Lohedan H.; Rajabathar J.R.; Zaidi S.A.; Sadasivuni K.K.
spellingShingle Geetha M.; Vashisht N.B.; Thanvir S.; Roslan N.C.; Mohamedzain T.H.; Alfarwati S.; Al-Lohedan H.; Rajabathar J.R.; Zaidi S.A.; Sadasivuni K.K.
Multi-functional nanoscale ZrO2 catalysts for sustainable water treatment
author_facet Geetha M.; Vashisht N.B.; Thanvir S.; Roslan N.C.; Mohamedzain T.H.; Alfarwati S.; Al-Lohedan H.; Rajabathar J.R.; Zaidi S.A.; Sadasivuni K.K.
author_sort Geetha M.; Vashisht N.B.; Thanvir S.; Roslan N.C.; Mohamedzain T.H.; Alfarwati S.; Al-Lohedan H.; Rajabathar J.R.; Zaidi S.A.; Sadasivuni K.K.
title Multi-functional nanoscale ZrO2 catalysts for sustainable water treatment
title_short Multi-functional nanoscale ZrO2 catalysts for sustainable water treatment
title_full Multi-functional nanoscale ZrO2 catalysts for sustainable water treatment
title_fullStr Multi-functional nanoscale ZrO2 catalysts for sustainable water treatment
title_full_unstemmed Multi-functional nanoscale ZrO2 catalysts for sustainable water treatment
title_sort Multi-functional nanoscale ZrO2 catalysts for sustainable water treatment
publishDate 2024
container_title Materials Chemistry and Physics
container_volume 316
container_issue
doi_str_mv 10.1016/j.matchemphys.2024.129096
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85185839924&doi=10.1016%2fj.matchemphys.2024.129096&partnerID=40&md5=675d16db24907c82eb0978adc545fa2a
description This study aimed to synthesize highly reactive ZrO2 nanoparticles using a straightforward sol-gel method for addressing water contamination from hazardous metal ions and organic dyes. Structural and photocatalytic properties were assessed using X-ray diffraction (XRD), Fourier transmission Infrared spectroscopy (FTIR), Transmission electron microscopy (TEM), and UV–visible absorption spectroscopy. XRD analysis confirmed the tetragonal crystal structure of ZrO2. Photodegradation experiments using Eriochrome Black T (EBT) as a model dye revealed nearly 99% degradation under natural sunlight. Investigations into catalyst loading, dye concentration, pH, and irradiation source were conducted. Preliminary tests demonstrated the adsorbent's efficacy in removing Ca2+ ions. Further process optimizations could significantly enhance the potential of this innovative adsorbent for extracting metal ions from complex effluents. © 2024 The Authors
publisher Elsevier Ltd
issn 2540584
language English
format Article
accesstype All Open Access
record_format scopus
collection Scopus
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