From recovered palladium to molecular and nanoscale catalysts
[PdI2(Me2dazdt)] is obtained from palladium powder via a 100% atom-economical Pd(0) leaching reaction using Me2dazdt (N,N′-dimethyl-perhydrodiazepine-2,3-dithione) and iodine. This complex is a versatile starting point for ligand exchange reactions with (di)phosphines, yielding trans-[PdI2(PPh3)2] a...
| Published in: | ACS Sustainable Chemistry and Engineering |
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| Main Author: | |
| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society
2019
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85073658576&doi=10.1021%2facssuschemeng.9b01877&partnerID=40&md5=18d28f845f26cee25080b4922faa624a |