Highly production of dihydroxystrearic acid from catalytic epoxidation process by in situ peracid mechanism

• 出版年: Environmental Progress and Sustainable Energy
• 第一著者: 2-s2.0-85116352643
• フォーマット: 論文
• 言語: English
• 出版事項: John Wiley and Sons Inc 2022
• オンライン･アクセス: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85116352643&doi=10.1002%2fep.13764&partnerID=40&md5=48a5695e5854e0a27cd7567129c3b989

Epoxidized vegetable oils are great concern as they are obtained from sustainable, and renewable natural resources. The epoxidation of palm oil-derived oleic acid was carried out by using in situ generated performic acid to produce epoxidized palm oil-derived oleic acid. The maximum conversion of palm oil-derived oleic acid into oxirane was 86% by applying the in situ peracid mechanism. Based on the Fourier-transform infrared spectrum, the hydroxyl group was observed within a wavenumber range of 1210–1320 cm−1. Last, a mathematical model was developed using Runge–Kutta method and after 100 iterations, the reaction rate parameters were obtained as follows: (Formula presented.) = 0.046 mol·L−1·min−1, (Formula presented.) = 39.058 mol·L−1·min−1, (Formula presented.) = 2.789 mol·L−1·min−1, and (Formula presented.) = 0.0235 mol·L−1·min−1 for of dihydroxystearic acid production. © 2021 American Institute of Chemical Engineers.