Highly production of dihydroxystrearic acid from catalytic epoxidation process by in situ peracid mechanism

Epoxidized vegetable oils are great concern as they are obtained from sustainable, and renewable natural resources. The epoxidation of palm oil-derived oleic acid was carried out by using in situ generated performic acid to produce epoxidized palm oil-derived oleic acid. The maximum conversion of pa...

詳細記述

書誌詳細
出版年:Environmental Progress and Sustainable Energy
第一著者: 2-s2.0-85116352643
フォーマット: 論文
言語:English
出版事項: John Wiley and Sons Inc 2022
オンライン・アクセス:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85116352643&doi=10.1002%2fep.13764&partnerID=40&md5=48a5695e5854e0a27cd7567129c3b989
その他の書誌記述
要約:Epoxidized vegetable oils are great concern as they are obtained from sustainable, and renewable natural resources. The epoxidation of palm oil-derived oleic acid was carried out by using in situ generated performic acid to produce epoxidized palm oil-derived oleic acid. The maximum conversion of palm oil-derived oleic acid into oxirane was 86% by applying the in situ peracid mechanism. Based on the Fourier-transform infrared spectrum, the hydroxyl group was observed within a wavenumber range of 1210–1320 cm−1. Last, a mathematical model was developed using Runge–Kutta method and after 100 iterations, the reaction rate parameters were obtained as follows: (Formula presented.) = 0.046 mol·L−1·min−1, (Formula presented.) = 39.058 mol·L−1·min−1, (Formula presented.) = 2.789 mol·L−1·min−1, and (Formula presented.) = 0.0235 mol·L−1·min−1 for of dihydroxystearic acid production. © 2021 American Institute of Chemical Engineers.
ISSN:19447442
DOI:10.1002/ep.13764