Physicochemical characterization and controlled release formulation on intercalated 2-methyl-4-chlorophenoxy acetic acid-graphite oxide (MCPA-GO) nanocomposite

• 出版年: Indonesian Journal of Chemistry
• 第一著者: 2-s2.0-85081229261
• フォーマット: 論文
• 言語: English
• 出版事項: Gadjah Mada University 2020
• オンライン･アクセス: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85081229261&doi=10.22146%2fijc.40921&partnerID=40&md5=d4b3f368f649e0813c8890f6bd189738

In this present work, herbicide named 2-methyl-4-chlorophenoxy acetic acid (MCPA) was intercalated into the graphite oxide through ion-exchange method to produce an MCPA-GO nanocomposite as an herbicide delivery system. The formation of MCPA-GO nanocomposite was confirmed by using PXRD, Fourier Transform Infrared Spectroscopy (FTIR), Thermal Gravimetric Analysis (TGA), UV-Visible Spectroscopy and Accelerated Surface Area Surface (ASAP). As for PXRD pattern, there was increasing in the basal spacing of the nanocomposite from the graphite oxide which by 9.3 to 9.7 Å indicated that MCPA has successfully inserted into the interlayers of the graphite oxide. Meanwhile, the FTIR spectrum showed the appearance of a new peak in MCPA-GO nanocomposite at 1308 cm–1 represents the functional group of carboxylate (COO–). This peak is very necessary for the confirmation of the anionic form of MCPA inserted into the interlayers of graphite oxide. The controlled release property was also done for further investigation by using various aqueous media to determine the percentage release of MCPA from the nanocomposite. The percentage of herbicide release in Na3PO3 solution was higher than in Na2CO3 and NaCl solution proved that the release properties exhibit the potential application of graphite oxide as effective nanocarrier of herbicides. MCPA-GO nanocomposite suggested being most promising herbicide since it can lower the toxicity of precursor MCPA, high biocompatibility, and more efficient in herbicide delivery system. © 2020, Gadjah Mada University. All rights reserved.