Vibrational Circular Dichorism for Absolute Configuration of (1S,2S)-Azido Trimethylsilylcyclohexene: Useful for Muricatacin Intermediate Synthesis

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Vibrational Circular Dichorism for Absolute Configuration of (1S,2S)-Azido Trimethylsilylcyclohexene: Useful for Muricatacin Intermediate Synthesis

A simple technique for absolute configuration determination of (1S,2S)-azido trimethylsilylcyclohexene 3 enantiomer is described. Samples were synthesized from racemic monoepoxide 1, via asymmetric epoxide ring opening catalyzed by (R,R)-salen complex, L-2 in the presence of trimethyl silylazide, TM...

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Bibliographic Details
Published in:	Malaysian Journal of Chemistry
Main Author:	Hussin Z.M.; Abd Haris S.A.-N.; Ghani F.S.A.; Hasan N.P.S.; Ali M.T.M.
Format:	Article
Language:	English
Published:	Malaysian Institute of Chemistry 2024
Online Access:	https://www.scopus.com/inward/record.uri?eid=2-s2.0-85209935219&doi=10.55373%2fmjchem.v26i5.533&partnerID=40&md5=ea63e4a09cf73c7cdcadf2b1c13a7a64

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