Vibrational Circular Dichorism for Absolute Configuration of (1S,2S)-Azido Trimethylsilylcyclohexene: Useful for Muricatacin Intermediate Synthesis
A simple technique for absolute configuration determination of (1S,2S)-azido trimethylsilylcyclohexene 3 enantiomer is described. Samples were synthesized from racemic monoepoxide 1, via asymmetric epoxide ring opening catalyzed by (R,R)-salen complex, L-2 in the presence of trimethyl silylazide, TM...
| Published in: | Malaysian Journal of Chemistry |
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| Main Author: | |
| Format: | Article |
| Language: | English |
| Published: |
Malaysian Institute of Chemistry
2024
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85209935219&doi=10.55373%2fmjchem.v26i5.533&partnerID=40&md5=ea63e4a09cf73c7cdcadf2b1c13a7a64 |