Thermolysis of Ru3(CO)10(µ-dppp): A new Ru4- cluster derived from 1,3-bis(diphenylphosphino)propane

The reaction of Ru3(CO)12 and dppp [dppp = 1,3-bis(diphenylphosphino)propane/Ph2P(CH2)3PPh2] in the presence of benzophenone ketyl radical anion afforded [Ru3(CO)11]2(µ-dppp) (1) Ru3(CO)10(µ-dppp) (2), Ru3(CO)9(µ-dppp)(ƞ1-dppp) (3) and Ru3(CO)8(µ-dppp)2 (4). Refluxing 2 in octane yields new triruthe...

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Bibliographic Details
Published in:Polyhedron
Main Author: Syaida Sirat S.; Izzati Muhammad Nor Azharan H.; Lee Sin A.; Arshad S.; Mustaqim Rosli M.; Nadia Md Yusof E.; Bin Shawkataly O.
Format: Article
Language:English
Published: Elsevier Ltd 2024
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85194941395&doi=10.1016%2fj.poly.2024.117066&partnerID=40&md5=8d248c93c3aa81c1536f779cfda19faf