Thermolysis of Ru3(CO)10(µ-dppp): A new Ru4- cluster derived from 1,3-bis(diphenylphosphino)propane
The reaction of Ru3(CO)12 and dppp [dppp = 1,3-bis(diphenylphosphino)propane/Ph2P(CH2)3PPh2] in the presence of benzophenone ketyl radical anion afforded [Ru3(CO)11]2(µ-dppp) (1) Ru3(CO)10(µ-dppp) (2), Ru3(CO)9(µ-dppp)(ƞ1-dppp) (3) and Ru3(CO)8(µ-dppp)2 (4). Refluxing 2 in octane yields new triruthe...
Published in: | Polyhedron |
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Main Author: | |
Format: | Article |
Language: | English |
Published: |
Elsevier Ltd
2024
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Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85194941395&doi=10.1016%2fj.poly.2024.117066&partnerID=40&md5=8d248c93c3aa81c1536f779cfda19faf |