Role of CA-EDTA on the synthesizing process of cerate-zirconate ceramics electrolyte

• Published in: Journal of Chemistry
• Main Author: Abdullah N.A.; Hasan S.; Osman N.
• Format: Article
• Language: English
• Published: 2013
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84870191668&doi=10.1155%2f2013%2f908340&partnerID=40&md5=ed24bc4dad9df5049c84887cb3ee03a9

The role of a combination between citric acid (CA) and ethylenediaminetetra acetic acid (EDTA) as chelating agents in preparation of BaCerpowder by a modified sol-gel method is reported. The precursor solutions were prepared from metal nitrate salts (M +), chelating agents (C), and ethylene glycol (EG) at molar ratio of M +: C: EG = 3: 2: 3. Chemical and phase transformation of samples during thermal decomposition were analyzed by thermogravimetric analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy. TGA results show that the sample prepared by a combination of CA-EDTA exhibited the lowest thermal decomposition temperature, T td since there was no significant weight loss after 750°C. After calcined at 1100°C, the carbonates residue remained in the samples as proven by FTIR results. It was found that the used combination of CA-EDTA acts as a better combustion reagent to increase the reaction rate and influence the thermal decomposition behaviour compared to a single citric acid and EDTA, respectively. Apparently, calcination temperatures above 1100°C are needed to produce a pure perovskitic BaCer © 2013 Nur Athirah Abdullah et al.