Correlation of the rates of solvolysis of (arylmethyl)methylphenyl-sulfonium ions
The specific rates of solvolysis of the benzylmethylphenylsulfonium ion (prepared as the trifluoromethanesulfonate salt) and five benzylic ring-substituted derivatives can be satisfactorily correlated using NT solvent nucleophilicity values. Addition of a secondary term, governed by the aromatic rin...
Published in: | Journal of the Chemical Society. Perkin Transactions 2 |
---|---|
Main Author: | |
Format: | Article |
Language: | English |
Published: |
Royal Society of Chemistry
1998
|
Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0040560233&doi=10.1039%2fa803859g&partnerID=40&md5=d1b81494c412a3e2610472b8670dcf3d |