Correlation of the rates of solvolysis of (arylmethyl)methylphenyl-sulfonium ions

The specific rates of solvolysis of the benzylmethylphenylsulfonium ion (prepared as the trifluoromethanesulfonate salt) and five benzylic ring-substituted derivatives can be satisfactorily correlated using NT solvent nucleophilicity values. Addition of a secondary term, governed by the aromatic rin...

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Bibliographic Details
Published in:Journal of the Chemical Society. Perkin Transactions 2
Main Author: Kevill D.N.; Ismail N.H.J.
Format: Article
Language:English
Published: Royal Society of Chemistry 1998
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-0040560233&doi=10.1039%2fa803859g&partnerID=40&md5=d1b81494c412a3e2610472b8670dcf3d