Freeze-drying synthesis of mesoporous magnetic grafted chitosan/calcium oxide nanoparticle for remazol brilliant blue dye removal: A statistical optimization

• Published in: INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
• Main Authors: Jawad, Ali H.; Maharani, Rosika Armiyanti; Hapiz, Ahmad; Khadiran, Tumirah; Jani, Nur Aimi; Alothman, Zeid A.; Wilson, Lee D.
• Format: Article
• Language: English
• Published: ELSEVIER 2025
• Subjects: Biochemistry & Molecular Biology; Chemistry; Polymer Science
• Online Access: https://www-webofscience-com.uitm.idm.oclc.org/wos/woscc/full-record/WOS:001386391100001
• ISSN: 0141-8130; 1879-0003
• DOI: 10.1016/j.ijbiomac.2024.138373

Herein, a mesoporous magnetic chitosan-salicylaldehyde/calcium oxide nanoparticle (CS-SL/CaO/Fe3O4) biocomposite adsorbent that was prepared via freeze-drying. The CS-SL/CaO/Fe3O4 was utilized for the adsorption of ramazol brilliant blue (RBB) dye from aqueous solution. The physicochemical properties of the CS-SL/CaO/ Fe3O4 were evaluated using diverse characterization techniques, including BET, XRD, FTIR, FESEM-EDX, CHNS, and pHpzc. The three main factors for adsorption included the following A: CS-SL/CaO/Fe3O4 dosage (0.02-0.1 g/100 mL), B: pH (4-10), and C: Time (60-540 min). These factors were improved using statistical methods, specifically the Box-Behnken design (BBD). The optimal conditions for achieving maximum RBB removal (62.5 %) are listed: CS-SL/CaO/Fe3O4 dosage of 0.1 g/100 mL, a solution pH of 7, and a contact time of 540 min. The adsorption kinetics and equilibrium isotherms were well described by the pseudo first order (PFO) kinetic and Langmuir isotherm models, respectively. Thus, the CS-SL/CaO/Fe3O4 material has a maximum adsorption capacity (qmax) of 63.3 mg/g for RBB at 25 degrees C. The adsorption mechanism of RBB onto the CS-SL/CaO/Fe3O4 surface was attributed to electrostatic forces, n-pi stacking, H-bonding, and Pi-Pi interactions. Thus, CS-SL/CaO/ Fe3O4 represents a recoverable magnetic adsorbent with potential for capture of organic dyes from wastewater.