Integrative approach to fluorescence-based oxygen sensing in polymer optical fibers with surface plasmon resonance
This study demonstrates a technique to enhance oxygen (O2) concentration measurement by combining surface plasmon resonance (SPR) and fluorescence-based sensor on polymer optical fiber (POF). The SPR was generated using silver (Ag) and the fluorescence was generated by organic dye. Three fluorescenc...
Published in: | SENSORS AND ACTUATORS A-PHYSICAL |
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Format: | Article |
Language: | English |
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ELSEVIER SCIENCE SA
2024
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Online Access: | https://www-webofscience-com.uitm.idm.oclc.org/wos/woscc/full-record/WOS:001347487200001 |
author |
Hishamuddin Azween Hadiera; Zoolfakar Ahmad Sabirin; Azeman Nur Hidayah; Bakar Mohd Hafiz Abu; Abdullah Fairuz; Daniyal Wan Mohd Ebtisyam Mustaqim Mohd; Bakar Ahmad Ashrif A.; Zolkapli Maizatul |
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Hishamuddin Azween Hadiera; Zoolfakar Ahmad Sabirin; Azeman Nur Hidayah; Bakar Mohd Hafiz Abu; Abdullah Fairuz; Daniyal Wan Mohd Ebtisyam Mustaqim Mohd; Bakar Ahmad Ashrif A.; Zolkapli Maizatul Integrative approach to fluorescence-based oxygen sensing in polymer optical fibers with surface plasmon resonance Engineering; Instruments & Instrumentation |
author_facet |
Hishamuddin Azween Hadiera; Zoolfakar Ahmad Sabirin; Azeman Nur Hidayah; Bakar Mohd Hafiz Abu; Abdullah Fairuz; Daniyal Wan Mohd Ebtisyam Mustaqim Mohd; Bakar Ahmad Ashrif A.; Zolkapli Maizatul |
author_sort |
Hishamuddin |
spelling |
Hishamuddin, Azween Hadiera; Zoolfakar, Ahmad Sabirin; Azeman, Nur Hidayah; Bakar, Mohd Hafiz Abu; Abdullah, Fairuz; Daniyal, Wan Mohd Ebtisyam Mustaqim Mohd; Bakar, Ahmad Ashrif A.; Zolkapli, Maizatul Integrative approach to fluorescence-based oxygen sensing in polymer optical fibers with surface plasmon resonance SENSORS AND ACTUATORS A-PHYSICAL English Article This study demonstrates a technique to enhance oxygen (O2) concentration measurement by combining surface plasmon resonance (SPR) and fluorescence-based sensor on polymer optical fiber (POF). The SPR was generated using silver (Ag) and the fluorescence was generated by organic dye. Three fluorescence dyes were used, Tris (4, 7-diphenyl-1, 10-phenanthroline) ruthenium (II) dichloride ([Ru(dpp)3]2+), platinum octaethylporphyrin (PtOEP) and 5,10,15,20-tetrakis (pentafluorophenyl) 21 H,23H-porphine palladium (II) (PdTFPP). The sensor was tested in a gas chamber with different concentration level of O2. Sensitivity values for the fluorescence dyes for [Ru(dpp)3]2*, PtOEP, and PdTFPP were 0.0099 a.u/%, 0.0343 a.u/% and 0.05 a.u/% respectively. When SPR was implemented, the sensitivity values for Ag/[Ru(dpp)3]2*, Ag/PtOEP, and Ag/PdTFPP were 0.0589 nm/%, 0.0345 nm/%, and 0.118 nm/% respectively. PdTFPP and Ag/PdTFPP exhibit highest sensitivity in each experiment. Therefore, the further analysis for the sensing performance of PdTFPP and Ag/PdTFPP were held. As a result, Ag/PdTFPP exhibits lower limit of detection (LOD), and limit of quantification (LOQ) with 3.054 % and 9.254 %, respectively, with higher R2 of 0.9971 and lower mean standard deviation of 0.174, compared to PdTFPP 16.496% and 49.988 % respectively, with R2 of 0.9211 and higher mean standard deviation of 2.003. This improvement can benefit researchers and professionals in medical diagnostics, environmental monitoring, and industrial process control by providing a more sensitive and accurate method for measuring O2 levels. ELSEVIER SCIENCE SA 0924-4247 1873-3069 2024 379 10.1016/j.sna.2024.115979 Engineering; Instruments & Instrumentation WOS:001347487200001 https://www-webofscience-com.uitm.idm.oclc.org/wos/woscc/full-record/WOS:001347487200001 |
title |
Integrative approach to fluorescence-based oxygen sensing in polymer optical fibers with surface plasmon resonance |
title_short |
Integrative approach to fluorescence-based oxygen sensing in polymer optical fibers with surface plasmon resonance |
title_full |
Integrative approach to fluorescence-based oxygen sensing in polymer optical fibers with surface plasmon resonance |
title_fullStr |
Integrative approach to fluorescence-based oxygen sensing in polymer optical fibers with surface plasmon resonance |
title_full_unstemmed |
Integrative approach to fluorescence-based oxygen sensing in polymer optical fibers with surface plasmon resonance |
title_sort |
Integrative approach to fluorescence-based oxygen sensing in polymer optical fibers with surface plasmon resonance |
container_title |
SENSORS AND ACTUATORS A-PHYSICAL |
language |
English |
format |
Article |
description |
This study demonstrates a technique to enhance oxygen (O2) concentration measurement by combining surface plasmon resonance (SPR) and fluorescence-based sensor on polymer optical fiber (POF). The SPR was generated using silver (Ag) and the fluorescence was generated by organic dye. Three fluorescence dyes were used, Tris (4, 7-diphenyl-1, 10-phenanthroline) ruthenium (II) dichloride ([Ru(dpp)3]2+), platinum octaethylporphyrin (PtOEP) and 5,10,15,20-tetrakis (pentafluorophenyl) 21 H,23H-porphine palladium (II) (PdTFPP). The sensor was tested in a gas chamber with different concentration level of O2. Sensitivity values for the fluorescence dyes for [Ru(dpp)3]2*, PtOEP, and PdTFPP were 0.0099 a.u/%, 0.0343 a.u/% and 0.05 a.u/% respectively. When SPR was implemented, the sensitivity values for Ag/[Ru(dpp)3]2*, Ag/PtOEP, and Ag/PdTFPP were 0.0589 nm/%, 0.0345 nm/%, and 0.118 nm/% respectively. PdTFPP and Ag/PdTFPP exhibit highest sensitivity in each experiment. Therefore, the further analysis for the sensing performance of PdTFPP and Ag/PdTFPP were held. As a result, Ag/PdTFPP exhibits lower limit of detection (LOD), and limit of quantification (LOQ) with 3.054 % and 9.254 %, respectively, with higher R2 of 0.9971 and lower mean standard deviation of 0.174, compared to PdTFPP 16.496% and 49.988 % respectively, with R2 of 0.9211 and higher mean standard deviation of 2.003. This improvement can benefit researchers and professionals in medical diagnostics, environmental monitoring, and industrial process control by providing a more sensitive and accurate method for measuring O2 levels. |
publisher |
ELSEVIER SCIENCE SA |
issn |
0924-4247 1873-3069 |
publishDate |
2024 |
container_volume |
379 |
container_issue |
|
doi_str_mv |
10.1016/j.sna.2024.115979 |
topic |
Engineering; Instruments & Instrumentation |
topic_facet |
Engineering; Instruments & Instrumentation |
accesstype |
|
id |
WOS:001347487200001 |
url |
https://www-webofscience-com.uitm.idm.oclc.org/wos/woscc/full-record/WOS:001347487200001 |
record_format |
wos |
collection |
Web of Science (WoS) |
_version_ |
1818940500845002752 |