Synthesis of novel CaF2 - CaO - Na2O - B2O3-SiO2 bioglass system: phase transformation, surface reaction and mechanical properties

• Published in: APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
• Main Authors: Loh, Zhi Wei; Zaid, Mohd Hafiz Mohd; Matori, Khamirul Amin; Cheong, Wei Mun; Mayzan, Mohd Zul Hilmi; Hisam, Rosdiyana
• Format: Article
• Language: English
• Published: SPRINGER HEIDELBERG 2024
• Subjects: Materials Science; Physics
• Online Access: https://www-webofscience-com.uitm.idm.oclc.org/wos/woscc/full-record/WOS:001227969300003
• ISSN: 0947-8396; 1432-0630
• DOI: 10.1007/s00339-024-07591-8

This research aims to investigate the potential of novel CaF2 - CaO - Na2O - B2O3-SiO2 glass systems and converted to bioactive glass-ceramics. The study involves examining the effects of different heat treatment temperatures and immersion periods, with the goal of exploring these materials as viable alternatives for various biomedical applications. A typical melt-quenching technique was used to synthesize the glass samples, followed by a controlled heat treatment. The main crystalline phases are cuspidine and wollastonite, which have the potential to promote bioactivity, especially in dental and bone-related applications. The sample heat-treated at 700 degrees C showed an increased microhardness and fracture toughness by more than 116% and 36%, compared to the initial value. Furthermore, the increase in pH and the observed weight loss/gain demonstrated the reactivity of the samples with the phosphate buffer-saline medium, indicating their bioactive properties. Remarkably, the microhardness and fracture toughness exhibited notable improvements after 14 days of immersion, with an enhancement of 4.71% and 4.66%, highlighting their potential durability and longevity in high-strength dental crown applications. Consequently, this research presents a promising method for developing sustainable novel glass and glass-ceramic materials devoid of phosphates. These materials boast enhanced mechanical properties while preserving bioactivity, making them well-suited for dental implants and restorative purposes.