Woody lignocellulosic waste conversion into activated carbon via microwave-assisted ZnCl2 activation: multivariable optimization for methylene blue dye removal

This study involved the conversion of lignocellulosic bamboo waste (BMW) into mesoporous activated carbon (BMWAC) via microwave-assisted ZnCl2 activation, where the BMWAC was evaluated for its removal of methylene blue (MB) dye from aqueous media. Various characterization techniques, including pH(pz...

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Published in:BIOMASS CONVERSION AND BIOREFINERY
Main Authors: Hapiz, Ahmad; Jawad, Ali H.; Wilson, Lee D.; Abdulhameed, Ahmed Saud; ALOthman, Zeid A.
Format: Article; Early Access
Language:English
Published: SPRINGER HEIDELBERG 2023
Subjects:
Online Access:https://www-webofscience-com.uitm.idm.oclc.org/wos/woscc/full-record/WOS:001196255000002
author Hapiz
Ahmad; Jawad
Ali H.; Wilson
Lee D.; Abdulhameed
Ahmed Saud; ALOthman
Zeid A.
spellingShingle Hapiz
Ahmad; Jawad
Ali H.; Wilson
Lee D.; Abdulhameed
Ahmed Saud; ALOthman
Zeid A.
Woody lignocellulosic waste conversion into activated carbon via microwave-assisted ZnCl2 activation: multivariable optimization for methylene blue dye removal
Energy & Fuels; Engineering
author_facet Hapiz
Ahmad; Jawad
Ali H.; Wilson
Lee D.; Abdulhameed
Ahmed Saud; ALOthman
Zeid A.
author_sort Hapiz
spelling Hapiz, Ahmad; Jawad, Ali H.; Wilson, Lee D.; Abdulhameed, Ahmed Saud; ALOthman, Zeid A.
Woody lignocellulosic waste conversion into activated carbon via microwave-assisted ZnCl2 activation: multivariable optimization for methylene blue dye removal
BIOMASS CONVERSION AND BIOREFINERY
English
Article; Early Access
This study involved the conversion of lignocellulosic bamboo waste (BMW) into mesoporous activated carbon (BMWAC) via microwave-assisted ZnCl2 activation, where the BMWAC was evaluated for its removal of methylene blue (MB) dye from aqueous media. Various characterization techniques, including pH(pzc), SEM-EDX, XRD, BET, and FTIR spectral analysis were employed to evaluate the properties of BMWAC. The results revealed that BMWAC is a mesoporous adsorbent with a significant surface area of 928 m(2)/g. To optimize its adsorption capacity, the Box-Behnken design (BBD) was used to modify three operational variables: BMWAC dosage, dye pH, and contact time. The kinetics of MB dye removal by BMWAC followed a pseudo-second-order model, while the equilibrium isotherm conformed to the Langmuir model. The maximal dye adsorption capacity (q(max)) of BMWAC with MB was found to be 285.1 mg/g, where the thermodynamics of the adsorption process was spontaneous and endothermic. The adsorption mechanism of MB dye by BMWAC was attributed to various processes that includes hydrogen bonding, electrostatic forces, pi-pi attraction, and pore filling. Overall, BMWAC was revealed for its effectiveness as an adsorbent for water treatment via efficient removal of cationic dyes from aqueous media.
SPRINGER HEIDELBERG
2190-6815
2190-6823
2023


10.1007/s13399-023-04868-5
Energy & Fuels; Engineering

WOS:001196255000002
https://www-webofscience-com.uitm.idm.oclc.org/wos/woscc/full-record/WOS:001196255000002
title Woody lignocellulosic waste conversion into activated carbon via microwave-assisted ZnCl2 activation: multivariable optimization for methylene blue dye removal
title_short Woody lignocellulosic waste conversion into activated carbon via microwave-assisted ZnCl2 activation: multivariable optimization for methylene blue dye removal
title_full Woody lignocellulosic waste conversion into activated carbon via microwave-assisted ZnCl2 activation: multivariable optimization for methylene blue dye removal
title_fullStr Woody lignocellulosic waste conversion into activated carbon via microwave-assisted ZnCl2 activation: multivariable optimization for methylene blue dye removal
title_full_unstemmed Woody lignocellulosic waste conversion into activated carbon via microwave-assisted ZnCl2 activation: multivariable optimization for methylene blue dye removal
title_sort Woody lignocellulosic waste conversion into activated carbon via microwave-assisted ZnCl2 activation: multivariable optimization for methylene blue dye removal
container_title BIOMASS CONVERSION AND BIOREFINERY
language English
format Article; Early Access
description This study involved the conversion of lignocellulosic bamboo waste (BMW) into mesoporous activated carbon (BMWAC) via microwave-assisted ZnCl2 activation, where the BMWAC was evaluated for its removal of methylene blue (MB) dye from aqueous media. Various characterization techniques, including pH(pzc), SEM-EDX, XRD, BET, and FTIR spectral analysis were employed to evaluate the properties of BMWAC. The results revealed that BMWAC is a mesoporous adsorbent with a significant surface area of 928 m(2)/g. To optimize its adsorption capacity, the Box-Behnken design (BBD) was used to modify three operational variables: BMWAC dosage, dye pH, and contact time. The kinetics of MB dye removal by BMWAC followed a pseudo-second-order model, while the equilibrium isotherm conformed to the Langmuir model. The maximal dye adsorption capacity (q(max)) of BMWAC with MB was found to be 285.1 mg/g, where the thermodynamics of the adsorption process was spontaneous and endothermic. The adsorption mechanism of MB dye by BMWAC was attributed to various processes that includes hydrogen bonding, electrostatic forces, pi-pi attraction, and pore filling. Overall, BMWAC was revealed for its effectiveness as an adsorbent for water treatment via efficient removal of cationic dyes from aqueous media.
publisher SPRINGER HEIDELBERG
issn 2190-6815
2190-6823
publishDate 2023
container_volume
container_issue
doi_str_mv 10.1007/s13399-023-04868-5
topic Energy & Fuels; Engineering
topic_facet Energy & Fuels; Engineering
accesstype
id WOS:001196255000002
url https://www-webofscience-com.uitm.idm.oclc.org/wos/woscc/full-record/WOS:001196255000002
record_format wos
collection Web of Science (WoS)
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