Co-production of biochar and carbon nanotube from sewage sludge in a two-stage process coupling pyrolysis and catalytic chemical vapor deposition

This study explores the potential of valorizing sewage sludge as a carbon source for the co-production of biochar and carbon nanomaterial via a two-stage thermal-catalytic process. In the first stage, sewage sludge underwent slow pyrolysis, resulting in a biochar yield of 66% (in weight) at 550 degr...

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Published in:WASTE DISPOSAL & SUSTAINABLE ENERGY
Main Authors: Ghazali, Mohd Syazwan Mohd; Zaini, Mohd Saufi Md; Arshad, Muhammad; Syed-Hassan, Syed Shatir A.
Format: Article; Early Access
Language:English
Published: SPRINGERNATURE 2024
Subjects:
Online Access:https://www-webofscience-com.uitm.idm.oclc.org/wos/woscc/full-record/WOS:001191030000001
author Ghazali
Mohd Syazwan Mohd; Zaini
Mohd Saufi Md; Arshad
Muhammad; Syed-Hassan
Syed Shatir A.
spellingShingle Ghazali
Mohd Syazwan Mohd; Zaini
Mohd Saufi Md; Arshad
Muhammad; Syed-Hassan
Syed Shatir A.
Co-production of biochar and carbon nanotube from sewage sludge in a two-stage process coupling pyrolysis and catalytic chemical vapor deposition
Science & Technology - Other Topics; Energy & Fuels; Environmental Sciences & Ecology
author_facet Ghazali
Mohd Syazwan Mohd; Zaini
Mohd Saufi Md; Arshad
Muhammad; Syed-Hassan
Syed Shatir A.
author_sort Ghazali
spelling Ghazali, Mohd Syazwan Mohd; Zaini, Mohd Saufi Md; Arshad, Muhammad; Syed-Hassan, Syed Shatir A.
Co-production of biochar and carbon nanotube from sewage sludge in a two-stage process coupling pyrolysis and catalytic chemical vapor deposition
WASTE DISPOSAL & SUSTAINABLE ENERGY
English
Article; Early Access
This study explores the potential of valorizing sewage sludge as a carbon source for the co-production of biochar and carbon nanomaterial via a two-stage thermal-catalytic process. In the first stage, sewage sludge underwent slow pyrolysis, resulting in a biochar yield of 66% (in weight) at 550 degrees C. The resulting pyrolysis vapor was then introduced into a second reactor, where catalytic chemical vapor deposition (CCVD) took place in the presence of a cobalt catalyst, leading to the production of carbon nanotubes (CNTs). It was found that CNTs with an inner diameter of similar to 3.2 nm and an outer diameter of 20-40 nm can be formed in the second stage reactor at temperatures between 650 degrees C and 950 degrees C with a maximum yield of 30% (in weight) under the employed experimental conditions. The obtained CNTs displayed a multiwall structure, exhibited a lack of crystallinity, and demonstrated a high level of disorder. The research findings also indicate that temperature exerts a significant influence on both the yield and properties of the CNTs synthesized.
SPRINGERNATURE
2524-7980
2524-7891
2024


10.1007/s42768-024-00194-2
Science & Technology - Other Topics; Energy & Fuels; Environmental Sciences & Ecology

WOS:001191030000001
https://www-webofscience-com.uitm.idm.oclc.org/wos/woscc/full-record/WOS:001191030000001
title Co-production of biochar and carbon nanotube from sewage sludge in a two-stage process coupling pyrolysis and catalytic chemical vapor deposition
title_short Co-production of biochar and carbon nanotube from sewage sludge in a two-stage process coupling pyrolysis and catalytic chemical vapor deposition
title_full Co-production of biochar and carbon nanotube from sewage sludge in a two-stage process coupling pyrolysis and catalytic chemical vapor deposition
title_fullStr Co-production of biochar and carbon nanotube from sewage sludge in a two-stage process coupling pyrolysis and catalytic chemical vapor deposition
title_full_unstemmed Co-production of biochar and carbon nanotube from sewage sludge in a two-stage process coupling pyrolysis and catalytic chemical vapor deposition
title_sort Co-production of biochar and carbon nanotube from sewage sludge in a two-stage process coupling pyrolysis and catalytic chemical vapor deposition
container_title WASTE DISPOSAL & SUSTAINABLE ENERGY
language English
format Article; Early Access
description This study explores the potential of valorizing sewage sludge as a carbon source for the co-production of biochar and carbon nanomaterial via a two-stage thermal-catalytic process. In the first stage, sewage sludge underwent slow pyrolysis, resulting in a biochar yield of 66% (in weight) at 550 degrees C. The resulting pyrolysis vapor was then introduced into a second reactor, where catalytic chemical vapor deposition (CCVD) took place in the presence of a cobalt catalyst, leading to the production of carbon nanotubes (CNTs). It was found that CNTs with an inner diameter of similar to 3.2 nm and an outer diameter of 20-40 nm can be formed in the second stage reactor at temperatures between 650 degrees C and 950 degrees C with a maximum yield of 30% (in weight) under the employed experimental conditions. The obtained CNTs displayed a multiwall structure, exhibited a lack of crystallinity, and demonstrated a high level of disorder. The research findings also indicate that temperature exerts a significant influence on both the yield and properties of the CNTs synthesized.
publisher SPRINGERNATURE
issn 2524-7980
2524-7891
publishDate 2024
container_volume
container_issue
doi_str_mv 10.1007/s42768-024-00194-2
topic Science & Technology - Other Topics; Energy & Fuels; Environmental Sciences & Ecology
topic_facet Science & Technology - Other Topics; Energy & Fuels; Environmental Sciences & Ecology
accesstype
id WOS:001191030000001
url https://www-webofscience-com.uitm.idm.oclc.org/wos/woscc/full-record/WOS:001191030000001
record_format wos
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