Effects of reaction conditions on the emission behaviors of arsenic, cadmium and lead during sewage sludge pyrolysis

Sewage sludge is an important class of bioresources whose energy content could be exploited using pyrolysis technology. However, some harmful trace elements in sewage sludge can escape easily to the gas phase during pyrolysis, increasing the potential of carcinogenic material emissions to the atmosp...

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书目详细资料
发表在:Bioresource Technology
主要作者: 2-s2.0-85017095242
格式: 文件
语言:English
出版: Elsevier Ltd 2017
在线阅读:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85017095242&doi=10.1016%2fj.biortech.2017.03.112&partnerID=40&md5=338fa8104c32d415fc1b28d9111c6efe
实物特征
总结:Sewage sludge is an important class of bioresources whose energy content could be exploited using pyrolysis technology. However, some harmful trace elements in sewage sludge can escape easily to the gas phase during pyrolysis, increasing the potential of carcinogenic material emissions to the atmosphere. This study investigates emission characteristics of arsenic, cadmium and lead under different pyrolysis conditions for three different sewage sludge samples. The increased temperature (within 723–1123 K) significantly promoted the cadmium and lead emissions, but its influence on arsenic emission was not pronounced. The releasing rate order of the three trace elements is volatile arsenic compounds > cadmium > lead in the beginning of pyrolysis. Fast heating rates promoted the emission of trace elements for the sludge containing the highest amount of ash, but exhibited an opposite effect for other studied samples. Overall, the high ash sludge released the least trace elements almost under all reaction conditions. © 2017 Elsevier Ltd
ISSN:9608524
DOI:10.1016/j.biortech.2017.03.112