Formation of zinc-aluminium layered double hydroxide-2,4,5- tricholorophenoxybutyrate nanocomposites by ion exchange method

The intercalation of herbicide, 2,4,5- tricholorophenoxybutyrate (TBA), into zincaluminium- layered double hydroxide (ZAL) for the formation of a new nanocomposite ZAT, was accomplished via anion exchange method. Due to the intercalation of TBA with ZAL interlayer domain, basal spacing expanded from...

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書目詳細資料
發表在:Advanced Materials Research
主要作者: 2-s2.0-84891600597
格式: Conference paper
語言:English
出版: Trans Tech Publications Ltd 2014
在線閱讀:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84891600597&doi=10.4028%2fwww.scientific.net%2fAMR.832.374&partnerID=40&md5=18f1fb5cd62536dce4d148156993a317
實物特徵
總結:The intercalation of herbicide, 2,4,5- tricholorophenoxybutyrate (TBA), into zincaluminium- layered double hydroxide (ZAL) for the formation of a new nanocomposite ZAT, was accomplished via anion exchange method. Due to the intercalation of TBA with ZAL interlayer domain, basal spacing expanded from 8.9Å in the ZAL to 23.3 Å in the ZAT. The percentage loading of TBA in the ZAT is 45.5 % (w/w). The FTIR spectra of the nanocomposite shows resemblance peaks of the TBA and Zn-Al-layered double hydroxide indicating the inclusion of TBA into the layered double hydroxide. Surface area of the resulting nanocomposite increased from 1.3 to 15.6 m2g-1 with the nitrogen adsorption-desorption of type IV, indicating the mesopore type of material. © (2014) Trans Tech Publications, Switzerland.
ISSN:10226680
DOI:10.4028/www.scientific.net/AMR.832.374