Adsorption of methylene blue onto betel nut husk-based activated carbon prepared by sodium hydroxide activation process

• 出版年: Water Science and Technology
• 第一著者: 2-s2.0-85096348692
• フォーマット: 論文
• 言語: English
• 出版事項: IWA Publishing 2020
• オンライン･アクセス: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85096348692&doi=10.2166%2fwst.2020.451&partnerID=40&md5=92f8bbb7ce3c8c3ffe3805433cf8e560

In this study, activated carbon (AC) was prepared from agro-waste betel nut husks (BNH) through the chemical activation method. Different characterization techniques described the physicochemical nature of betel nut husks activated carbon (BNH-AC) through Fourier transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM), and pH point of zero charge. Later, the produced AC was used for methylene blue (MB) adsorption via numerous batch experimental parameters: initial concentrations of MB dye (25-250 mg/L), contact time (0.5-24 hours) and initial pH (2-12). Dye adsorption isotherms were also assessed at three temperatures where the maximum adsorption capacity (381.6 mg/g) was found at 30 °C. The adsorption equilibrium data were best suited to the non-linear form of the Freundlich isotherm model. Additionally, non-linear pseudo-second-order kinetic model was better fitted with the experimental value as well. Steady motion of solute particles from the boundary layer to the BNH-AC's surface was the possible reaction dynamics concerning MB adsorption. Thermodynamic study revealed that the adsorption process was spontaneous and exothermic in nature. Saline water emerged as an efficient eluent for the desorption of adsorbed dye on AC. Therefore, the BNH-AC is a very promising and cost-effective adsorbent for MB dye treatment and has high adsorption capacity. © 2020 IWA Publishing. All rights reserved.