Permeation of Chlorinated Hydrocarbon Vapors through High Density Polyethylene/Ethylene Propylene Diene Terpolymer Rubber Blends

Polymer membranes were prepared by blending high density polyethylene (HDPE) with ethylene propylene diene terpolymer rubber (EPDM) and were tested for vapor permeation characteristics. The variation in sorption, diffusion, and permeation coefficients with blend composition has been studied and it w...

وصف كامل

التفاصيل البيبلوغرافية
الحاوية / القاعدة:Separation Science and Technology
المؤلف الرئيسي: 2-s2.0-84860142920
التنسيق: مقال
اللغة:English
منشور في: 2012
الوصول للمادة أونلاين:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84860142920&doi=10.1080%2f01496395.2011.630053&partnerID=40&md5=65cd3964e2051945345fd8c8b5b7ef0a
الوصف
الملخص:Polymer membranes were prepared by blending high density polyethylene (HDPE) with ethylene propylene diene terpolymer rubber (EPDM) and were tested for vapor permeation characteristics. The variation in sorption, diffusion, and permeation coefficients with blend composition has been studied and it was found that in these blends the permeability coefficient and sorption coefficients increased with increase in EPDM concentration. The permeation rate decreased with the increase in molecular mass of the penetrants. The permeability of the HDPE/EPDM blends vulcanized with three different vulcanizing systems has been studied and found that as the degree of crosslinking increases, the permeability decreases. The permeability measurements provide useful information on the morphology changes with composition of the blends and on the composition corresponding to the maximum level of co-continuity of the two phases. © 2012 Copyright Taylor and Francis Group, LLC.
تدمد:15205754
DOI:10.1080/01496395.2011.630053