Freeze-drying synthesis of mesoporous magnetic grafted chitosan/calcium oxide nanoparticle for remazol brilliant blue dye removal: A statistical optimization

• Published in: International Journal of Biological Macromolecules
• Main Author: Jawad A.H.; Maharani R.A.; Hapiz A.; Khadiran T.; Jani N.A.; ALOthman Z.A.; Wilson L.D.
• Format: Article
• Language: English
• Published: Elsevier B.V. 2025
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85211450926&doi=10.1016%2fj.ijbiomac.2024.138373&partnerID=40&md5=d75f70235893e9feb595da1396e95d2c

Herein, a mesoporous magnetic chitosan-salicylaldehyde/calcium oxide nanoparticle (CS-SL/CaO/Fe3O4) biocomposite adsorbent that was prepared via freeze-drying. The CS-SL/CaO/Fe3O4 was utilized for the adsorption of ramazol brilliant blue (RBB) dye from aqueous solution. The physicochemical properties of the CS-SL/CaO/Fe3O4 were evaluated using diverse characterization techniques, including BET, XRD, FTIR, FESEM-EDX, CHNS, and pHpzc. The three main factors for adsorption included the following A: CS-SL/CaO/Fe3O4 dosage (0.02–0.1 g/100 mL), B: pH (4–10), and C: Time (60–540 min). These factors were improved using statistical methods, specifically the Box-Behnken design (BBD). The optimal conditions for achieving maximum RBB removal (62.5 %) are listed: CS-SL/CaO/Fe3O4 dosage of 0.1 g/100 mL, a solution pH of 7, and a contact time of 540 min. The adsorption kinetics and equilibrium isotherms were well described by the pseudo first order (PFO) kinetic and Langmuir isotherm models, respectively. Thus, the CS-SL/CaO/Fe3O4 material has a maximum adsorption capacity (qmax) of 63.3 mg/g for RBB at 25 °C. The adsorption mechanism of RBB onto the CS-SL/CaO/Fe3O4 surface was attributed to electrostatic forces, n-π stacking, H-bonding, and Pi-Pi interactions. Thus, CS-SL/CaO/Fe3O4 represents a recoverable magnetic adsorbent with potential for capture of organic dyes from wastewater. © 2024 Elsevier B.V.