Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-ylidene]-hydrazinecarbodithioate
The title dithiocarbazate imine, C11H11N3OS2, was obtained from the condensation reaction of S-methyldithiocarbazate (SMDTC) and 5-methylisatin. It shows a Z configuration about the imine C=N bond, which is associated with an intramolecular N—H. . .O hydrogen bond that closes an S(6) ring. In the cr...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2024
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85210604786&doi=10.1107%2fS2414314624009672&partnerID=40&md5=8e22d2b96f1c40f1a39e100ae3b01d81 |
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2-s2.0-85210604786 |
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2-s2.0-85210604786 Manan M.A.F.A.; Cordes D.B.; McKay A.P. Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-ylidene]-hydrazinecarbodithioate 2024 IUCrData 9 10 10.1107/S2414314624009672 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85210604786&doi=10.1107%2fS2414314624009672&partnerID=40&md5=8e22d2b96f1c40f1a39e100ae3b01d81 The title dithiocarbazate imine, C11H11N3OS2, was obtained from the condensation reaction of S-methyldithiocarbazate (SMDTC) and 5-methylisatin. It shows a Z configuration about the imine C=N bond, which is associated with an intramolecular N—H. . .O hydrogen bond that closes an S(6) ring. In the crystal, inversion dimers linked by pairwise N—H. . .O hydrogen bonds generate R22(8) loops. The extended structure features C—H. . .S contacts as well as reciprocal carbonyl–carbonyl (C=O. . .C=O) interactions. (Figure Presented) © 2024 International Union of Crystallography. All rights reserved. International Union of Crystallography 24143146 English Article All Open Access; Gold Open Access |
| author |
Manan M.A.F.A.; Cordes D.B.; McKay A.P. |
| spellingShingle |
Manan M.A.F.A.; Cordes D.B.; McKay A.P. Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-ylidene]-hydrazinecarbodithioate |
| author_facet |
Manan M.A.F.A.; Cordes D.B.; McKay A.P. |
| author_sort |
Manan M.A.F.A.; Cordes D.B.; McKay A.P. |
| title |
Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-ylidene]-hydrazinecarbodithioate |
| title_short |
Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-ylidene]-hydrazinecarbodithioate |
| title_full |
Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-ylidene]-hydrazinecarbodithioate |
| title_fullStr |
Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-ylidene]-hydrazinecarbodithioate |
| title_full_unstemmed |
Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-ylidene]-hydrazinecarbodithioate |
| title_sort |
Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-ylidene]-hydrazinecarbodithioate |
| publishDate |
2024 |
| container_title |
IUCrData |
| container_volume |
9 |
| container_issue |
10 |
| doi_str_mv |
10.1107/S2414314624009672 |
| url |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85210604786&doi=10.1107%2fS2414314624009672&partnerID=40&md5=8e22d2b96f1c40f1a39e100ae3b01d81 |
| description |
The title dithiocarbazate imine, C11H11N3OS2, was obtained from the condensation reaction of S-methyldithiocarbazate (SMDTC) and 5-methylisatin. It shows a Z configuration about the imine C=N bond, which is associated with an intramolecular N—H. . .O hydrogen bond that closes an S(6) ring. In the crystal, inversion dimers linked by pairwise N—H. . .O hydrogen bonds generate R22(8) loops. The extended structure features C—H. . .S contacts as well as reciprocal carbonyl–carbonyl (C=O. . .C=O) interactions. (Figure Presented) © 2024 International Union of Crystallography. All rights reserved. |
| publisher |
International Union of Crystallography |
| issn |
24143146 |
| language |
English |
| format |
Article |
| accesstype |
All Open Access; Gold Open Access |
| record_format |
scopus |
| collection |
Scopus |
| _version_ |
1820775432220311552 |