Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-ylidene]-hydrazinecarbodithioate
The title dithiocarbazate imine, C11H11N3OS2, was obtained from the condensation reaction of S-methyldithiocarbazate (SMDTC) and 5-methylisatin. It shows a Z configuration about the imine C=N bond, which is associated with an intramolecular N—H. . .O hydrogen bond that closes an S(6) ring. In the cr...
| Published in: | IUCrData |
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| Main Author: | |
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2024
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85210604786&doi=10.1107%2fS2414314624009672&partnerID=40&md5=8e22d2b96f1c40f1a39e100ae3b01d81 |
| Summary: | The title dithiocarbazate imine, C11H11N3OS2, was obtained from the condensation reaction of S-methyldithiocarbazate (SMDTC) and 5-methylisatin. It shows a Z configuration about the imine C=N bond, which is associated with an intramolecular N—H. . .O hydrogen bond that closes an S(6) ring. In the crystal, inversion dimers linked by pairwise N—H. . .O hydrogen bonds generate R22(8) loops. The extended structure features C—H. . .S contacts as well as reciprocal carbonyl–carbonyl (C=O. . .C=O) interactions. (Figure Presented) © 2024 International Union of Crystallography. All rights reserved. |
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| ISSN: | 24143146 |
| DOI: | 10.1107/S2414314624009672 |