| Summary: | The title compound, C10H8BrN3OS2, a brominated dithiocarbazate imine derivative, was obtained from the condensation reaction of S-methyldithiocarbazate (SMDTC) and 5-bromoisatin. The essentially planar molecule exhibits a Z configuration, with the dithiocarbazate and 5-bromoisatin fragments located on the same sides of the C=N azomethine bond, which allows for the formation of an intramolecular N - H⋯Ob (b = bromoisatin) hydrogen bond generating an S(6) ring motif. In the crystal, adjacent molecules are linked by pairs of N - H⋯O hydrogen bonds, forming dimers characterized by an R22 (8) loop motif. In the extended structure, molecules are linked into a three-dimensional network by C - H⋯S and C - H⋯Br hydrogen bonds, C - Br⋯S halogen bonds and aromatic π-π stacking. © Abdul Manan et al. 2024.
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