Exploring the effect of the bromo- and iodo-halide(s) in the two-dimensional hybrid perovskites (H2-2AMP)PbX4 (X=Br and I) into the structural, chemical and optical properties

The influence of bromide and iodide-halides on (H2-2AMP)PbX4 (X = Br and I) compounds, focusing on their structural, chemical, and optical characteristics was investigated in this study. Synthesized via a reflux method under a nitrogen atmosphere, the compounds were analyzed using FT-IR spectroscopy...

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Bibliographic Details
Published in:Journal of Solid State Chemistry
Main Author: Ramli A.; Wan Ismail W.I.N.; Sepeai S.; Abdul Yami N.F.N.; Ali A.M.M.
Format: Article
Language:English
Published: Academic Press Inc. 2024
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85198315809&doi=10.1016%2fj.jssc.2024.124877&partnerID=40&md5=f184dc15fca109836c864a89758778eb
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Summary:The influence of bromide and iodide-halides on (H2-2AMP)PbX4 (X = Br and I) compounds, focusing on their structural, chemical, and optical characteristics was investigated in this study. Synthesized via a reflux method under a nitrogen atmosphere, the compounds were analyzed using FT-IR spectroscopy and XRD analysis. Despite differing halides, both compounds share an orthorhombic crystal structure, with distinct cell parameters and bond lengths. The UV–Vis analysis reveals significant tuning of the cut edge within the visible range, offering insights into their potential of the materials in optoelectronic applications. © 2024 Elsevier Inc.
ISSN:224596
DOI:10.1016/j.jssc.2024.124877