Ag-doped TiO2with Tuneable Ag0and Ag+for Enhanced Photocatalytic Degradation of RR4 Dye

• Published in: Malaysian Journal of Chemistry
• Main Author: Ghani N.I.I.; Zanal N.I.N.; Md Natar N.S.; Hamzah S.R.; Rosli M.A.; Muhamad N.A.; Mohd Azami M.S.; Mohamad S.; Ismail W.I.N.W.
• Format: Article
• Language: English
• Published: Malaysian Institute of Chemistry 2024
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85190889269&doi=10.55373%2fmjchem.v26i2.12&partnerID=40&md5=2a1c6a0a87229f8d06b21e67dd485502

This study proposed to enhance the photocatalytic performance of Ag-TiO2by manipulating Ag0and Ag+formation on TiO2through controlled dissolved oxygen (DO) levels by photo- deposition of Ag (1-5 wt.%) to TiO2under N2gas purging (0-60 min; denoted as DO0-DO60). The photocatalytic performance of the immobilised Ag-TiO2was determined under the photodegradation of Reactive Red 4 (RR4) dye. XRD and FTIR revealed the existence of Ag+and Ag0, corresponding to Ag2O and Ag-TiO2, respectively. The HRTEM images showed a spheroid shape of Ag-TiO2with 0.20 and 0.24 nm of d-spacing, representing Ag metal and Ag2O, respectively. The lower PL intensity of Ag-TiO2suggested a reduced e-/h+recombination rate, while UV-Vis/DRS analysis indicated strong visible light absorption due to the surface plasmonic resonance (SPR) effect. This study proves that Ag2O can increase photocatalytic performance as an electron injector to Ag-TiO2, however, excess formation of Ag2O can retard the photocatalytic activity. Optimal 3 wt.% Ag doping at 30 min N 2 purging (3AT-DO30) achieved complete 30 mg L-1RR4 dye degradation in 1 hour, surpassing unmodified TiO2by 63.1%. The photocatalytic performance order was TiO2< 3AT-DO60< 3AT-DO0< 3AT-DO10< 3AT-DO30, with all samples maintaining stability over 10 cycles. © 2024 Malaysian Institute of Chemistry. All rights reserved.