4-Fluorobenzyl (Z)-2-(2-oxoindolin-3-ylidene) hydrazine-1-carbodithioate

• Published in: IUCrData
• Main Author: Manan M.A.F.A.; Cordes D.B.; McKay A.P.
• Format: Article
• Language: English
• Published: International Union of Crystallography 2024
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85189660845&doi=10.1107%2fS2414314624002359&partnerID=40&md5=a4062051964fdb0a6a4466a0b129b329

The title compound, C16H12FN3OS, a fluorinated dithiocarbazate imine derivative, was synthesized by the one-pot, multi-component condensation reaction of hydrazine hydrate, carbon disulfide, 4-fluorobenzyl chloride and isatin. The compound demonstrates near-planarity across much of the molecule in the solid state and a Z configuration for the azomethine C N bond. The Z form is further stabilized by the presence of an intramolecular N—H. . .O hydrogen bond. In the extended structure, molecules are linked into dimers by N—H. . .O hydrogen bonds and further connected into chains along either [210] or [100] by weak C—H. . .S and C—H. . .F hydrogen bonds, which further link into corrugated sheets and in combination form the overall three-dimensional network. © 2024 International Union of Crystallography. All rights reserved.