| Summary: | In this study, a cross-linked chitosan-epichlorohydrin/nanosilica (CS-EPH/NSi) bionanocomposite was prepared using a simple two-step process. First, functionalization of chitosan with nanosilica followed by crosslinking process with epichlorohydrin. The CS-EPH/NSi bionanocomposite’s adsorption property toward the removal of reactive orange 16 (RO16) dye was evaluated. The adsorption process of RO16 by CS-EPH/NSi was optimized using Box-Behnken design (BBD). The desirability function results revealed that the highest removal of RO16 (96.32%) is achieved at the following experimental conditions: solution pH of 4.26, dosage of CS-EPH/NSi = 0.089 g/100 mL, and contact time of 9.69 min. The Langmuir isotherm model was found to describe the equilibrium behavior of the monolayer adsorption process at 25 °C. The kinetics data of RO16 adsorption by CS-EPH/NSi were appropriately described by a pseudo-second order model, which suggests that the adsorption process occurs via chemisorption. The high adsorption capacity of CS-EPH/NSi for RO16 (110.2 mg/g) can be attributed to the electrostatic forces between the positively charged CS-EPH/NSi and the negatively charged RO16 anions, as well as n-π and H-bond interactions. Overall, this study demonstrates the potential of CS-EPH/NSi as an adsorbent for the efficient removal of textile RO16 dye. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024.
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