Color Changes, AFM and SEM Study of PVC/triorganotin (IV) - Cephalexin Complexes Samples Via UV Radiation

Color Changes, AFM and SEM Study of PVC/triorganotin (IV) - Cephalexin Complexes Samples Via UV Radiation

Three organotin complexes were successfully produced in the presence of sodium hydroxide by the condensation reaction of cephalexin (ligand) and tri-organotin (IV) complexes. The complexes formed were given trigonal bipyramidal geometries based on spectrum measurements. These compounds were applied...

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Published in:Progress in Color, Colorants and Coatings
Main Author: Arraq R.R.; Hadi A.G.; Ahmed D.S.; Al-Mashhadani M.H.; Hashim H.; Ahmed A.A.; Husain A.; Baqir S.J.; Jawad A.H.; Yousif E.
Format: Article
Language:English
Published: Institute for Color Science and Technology 2023
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85167927429&doi=10.30509%2fpccc.2023.167075.1195&partnerID=40&md5=34cf60ea89a76f1fe1cf47327fb4d703
id 2-s2.0-85167927429
spelling 2-s2.0-85167927429
Arraq R.R.; Hadi A.G.; Ahmed D.S.; Al-Mashhadani M.H.; Hashim H.; Ahmed A.A.; Husain A.; Baqir S.J.; Jawad A.H.; Yousif E.
Color Changes, AFM and SEM Study of PVC/triorganotin (IV) - Cephalexin Complexes Samples Via UV Radiation
2023
Progress in Color, Colorants and Coatings
16
3
10.30509/pccc.2023.167075.1195
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85167927429&doi=10.30509%2fpccc.2023.167075.1195&partnerID=40&md5=34cf60ea89a76f1fe1cf47327fb4d703
Three organotin complexes were successfully produced in the presence of sodium hydroxide by the condensation reaction of cephalexin (ligand) and tri-organotin (IV) complexes. The complexes formed were given trigonal bipyramidal geometries based on spectrum measurements. These compounds were applied as additives (0.5 percent by weight) to reduce the photodegradation of polyvinyl chloride films (40 μm thickness) when exposed to ultraviolet light at a normal temperature (max = 313 at an intensity of light = 7.75 × 10-7 ein dm-3 S-1). The weight changes of films before and after irradiation can be applied to investigate the effectiveness of organotin (IV) complexes as photo stabilizers. After irradiation, the morphology of poly(vinyl chloride) studied by the microscope, atomic force microscopy, and scanning electron microscope was shown to be less damaged in the films containing additives. These additives are effective UV absorbers, hydrogen chloride scavengers, and peroxide quenchers. © Institute for Color Science and Technology.
Institute for Color Science and Technology
20082134
English
Article
author Arraq R.R.; Hadi A.G.; Ahmed D.S.; Al-Mashhadani M.H.; Hashim H.; Ahmed A.A.; Husain A.; Baqir S.J.; Jawad A.H.; Yousif E.
spellingShingle Arraq R.R.; Hadi A.G.; Ahmed D.S.; Al-Mashhadani M.H.; Hashim H.; Ahmed A.A.; Husain A.; Baqir S.J.; Jawad A.H.; Yousif E.
Color Changes, AFM and SEM Study of PVC/triorganotin (IV) - Cephalexin Complexes Samples Via UV Radiation
author_facet Arraq R.R.; Hadi A.G.; Ahmed D.S.; Al-Mashhadani M.H.; Hashim H.; Ahmed A.A.; Husain A.; Baqir S.J.; Jawad A.H.; Yousif E.
author_sort Arraq R.R.; Hadi A.G.; Ahmed D.S.; Al-Mashhadani M.H.; Hashim H.; Ahmed A.A.; Husain A.; Baqir S.J.; Jawad A.H.; Yousif E.
title Color Changes, AFM and SEM Study of PVC/triorganotin (IV) - Cephalexin Complexes Samples Via UV Radiation
title_short Color Changes, AFM and SEM Study of PVC/triorganotin (IV) - Cephalexin Complexes Samples Via UV Radiation
title_full Color Changes, AFM and SEM Study of PVC/triorganotin (IV) - Cephalexin Complexes Samples Via UV Radiation
title_fullStr Color Changes, AFM and SEM Study of PVC/triorganotin (IV) - Cephalexin Complexes Samples Via UV Radiation
title_full_unstemmed Color Changes, AFM and SEM Study of PVC/triorganotin (IV) - Cephalexin Complexes Samples Via UV Radiation
title_sort Color Changes, AFM and SEM Study of PVC/triorganotin (IV) - Cephalexin Complexes Samples Via UV Radiation
publishDate 2023
container_title Progress in Color, Colorants and Coatings
container_volume 16
container_issue 3
doi_str_mv 10.30509/pccc.2023.167075.1195
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85167927429&doi=10.30509%2fpccc.2023.167075.1195&partnerID=40&md5=34cf60ea89a76f1fe1cf47327fb4d703
description Three organotin complexes were successfully produced in the presence of sodium hydroxide by the condensation reaction of cephalexin (ligand) and tri-organotin (IV) complexes. The complexes formed were given trigonal bipyramidal geometries based on spectrum measurements. These compounds were applied as additives (0.5 percent by weight) to reduce the photodegradation of polyvinyl chloride films (40 μm thickness) when exposed to ultraviolet light at a normal temperature (max = 313 at an intensity of light = 7.75 × 10-7 ein dm-3 S-1). The weight changes of films before and after irradiation can be applied to investigate the effectiveness of organotin (IV) complexes as photo stabilizers. After irradiation, the morphology of poly(vinyl chloride) studied by the microscope, atomic force microscopy, and scanning electron microscope was shown to be less damaged in the films containing additives. These additives are effective UV absorbers, hydrogen chloride scavengers, and peroxide quenchers. © Institute for Color Science and Technology.
publisher Institute for Color Science and Technology
issn 20082134
language English
format Article
accesstype
record_format scopus
collection Scopus
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