Magnetic grafted chitosan-salicylaldehyde via hydrothermal synthesis for acid red 88 dye removal: a statistical optimization

• Published in: Biomass Conversion and Biorefinery
• Main Author: Hapiz A.; Arni L.A.; Khadiran T.; ALOthman Z.A.; Wilson L.D.; Jawad A.H.
• Format: Article
• Language: English
• Published: Springer Science and Business Media Deutschland GmbH 2024
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85160837725&doi=10.1007%2fs13399-023-04352-0&partnerID=40&md5=b341dbf1d31cf0baec01833f845f8e7b

Herein, an aromatic ring aldehyde (salicylaldehyde, SL) was grafted onto the biopolymer matrix of the magnetic chitosan (CS/Fe3O4) to yield a recoverable promising adsorbent for the removal of acid red 88 (AR88 dye) from aqueous media. Various characterization methods such as VSM, pHpzc, CHNS, XRD, SEM–EDX, FTIR, and BET were used to determine the physicochemical properties of CS-SL/Fe3O4. A Box-Behnken design (BBD) was adopted to optimize the experimental parameters of A: CS-SL/Fe3O4 dose (0.02–0.1 g), B: [AR88] concentration (10–50 mg/L), C: pH (4–10), and D: contact time (10–90 min) on the adsorption performance of CS-SL/Fe3O4 with the AR88 dye. The Freundlich isotherm and pseudo-second-order kinetic models were applicable to describe the dye adsorption rate of AR888. The maximum dye adsorption capacity (qmax) of the hydrothermally grafted CS-SL/Fe3O4 with AR88 was 137.3 mg/g at a fixed adsorbent dosage (0.09 g) and pH (4.16). Various intermolecular interactions such as electrostatic, π-π stacking, n-π interactions, and H-bonding contribute to AR88 adsorption by CS-SL/Fe3O4. This study introduces a recoverable and a promising magnetic grafted chitosan adsorbent for the removal of an anionic dye from aqueous media. Moreover, this adsorbent can be further applied to the removal of other types of water contaminants in aquatic environmental media. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023.