Benzil Schiff Base Side-Chain Polymer-Crosslinked Chitosan Via Hydrothermal Process for Reactive Orange 16 Dye Removal: An Optimized and Comparative Study with Chitosan

• Published in: Journal of Polymers and the Environment
• Main Author: Normi N.I.; Abdulhameed A.S.; Surip S.N.; ALOthman Z.A.; Wilson L.D.; Jawad A.H.
• Format: Article
• Language: English
• Published: Springer 2023
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85144232226&doi=10.1007%2fs10924-022-02727-4&partnerID=40&md5=198d7245e3215a2a6a7765fa7238d49a

Herein, a novel hydrothermally cross-linked chitosan-benzil (CTS-BZ) was prepared by a facile hydrothermal process. The physicochemical characteristics of the developed adsorbents were analyzed using CHN-O, BET, XRD, FTIR, pHpzc, and SEM analytical techniques. The characterization results demonstrated the mesoporous and crystal line nature of the CTS-BZ as well as the successful grafting of the aromatic ring of the BZ onto the CTS chains. The hydrothermally cross-linked CTS-BZ and chitosan (CTS) were employed for the removal of reactive orange 16 (RO16) dye in a comparative way. Response surface methodology (RSM) was adopted in collaboration with Box-Behnken design (BBD) to optimize the important parameters impacting RO16 adsorption, namely; adsorbent dose (A: 0.02–0.08 g), pH (B: 4–10), and time (C: 5–25). The Langmuir and Freundlich models accurately described the isotherm adsorption data of RO16 by CTS and RO16 by CTS-BZ, respectively. Kinetic adsorption results for RO16 by both CTS beads and CTS-BZ were well-described by the pseudo-second-order model. Remarkably, the hydrothermally cross-linked CTS-BZ revealed a maximum adsorption capacity for RO16 of 291.8 mg/g, as compared with the CTS’s adsorption capacity of 227.5 mg/g. The adsorption of RO16 onto the hydrothermally cross-linked CTS-BZ surface is largely controlled by a variety of mechanisms including electrostatic forces, H-bonding, π-π stacking, and n-π interactions. This study shows that novel hydrothermally cross-linked CTS-BZ outperforms pristine CTS beads as a very effective adsorbent for the removal of hazardous contaminants from water. © 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.