| Summary: | Ground-level ozone (O3) is one of the most significant forms of air pollution around the world due to its ability to cause adverse effects on human health and environment. Understanding the variation and association of O3 level with its precursors and weather parameters is important for developing precise forecasting models that are needed for mitigation planning and early warning purposes. In this study, hourly air pollution data (O3, CO, NO2, PM10, NmHC, SO2) and weather parameters (relative humidity, temperature, UVB, wind speed and wind direction) covering a ten year period (2003–2012) in the selected urban areas in Malaysia were analyzed. The main aim of this research was to model O3 level in the band of greatest solar radiation with its precursors and meteorology parameters using the proposed predictive models. Six predictive models were developed which are Multiple Linear Regression (MLR), Feed-Forward Neural Network (FFANN), Radial Basis Function (RBFANN), and the three modified models, namely Principal Component Regression (PCR), PCA-FFANN, and PCA-RBFANN. The performances of the models were evaluated using four performance measures, i.e., Mean Absolute Error (MAE), Root Mean Squared Error (RMSE), Index of Agreement (IA), and Coefficient of Determination (R2). Surface O3 level was best described using linear regression model (MLR) with the smallest calculated error (MAE = 6.06; RMSE = 7.77) and the highest value of IA and R2 (0.85 and 0.91 respectively). The non-linear models (FFANN and RBFANN) fitted the observed O3 level well, but were slightly less accurate compared to MLR. Nonetheless, all the unmodified models (MLR, ANN, and RBF) outperformed the modified-version models (PCR, PCA-FFANN, and PCA-RBFANN). Verification of the best model (MLR) was done using air pollutant data in 2018. The MLR model fitted the dataset of 2018 very well in predicting the daily O3 level in the specified selected areas with the range of R2 values of 0.85 to 0.95. These indicate that MLR can be used as one of the reliable methods to predict daytime O3 level in Malaysia. Thus, it can be used as a predictive tool by the authority to forecast high ozone concentration in providing early warning to the population. © 2022 by the authors. Licensee MDPI, Basel, Switzerland.
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