The impact of zr substitution on the crystal structure of yb doped baceo3 solid solution prepared by a sol-gel method

The impact of zr substitution on the crystal structure of yb doped baceo3 solid solution prepared by a sol-gel method

A modified sol-gel method using metal nitrate salts was adopted to synthesis proton conductor of Ba(Ce1-xZrx)0.95Yb0.05O2.975 where x=0.2, 0.3, 0.4, 0.5 and 0.6 ceramic powders. The aim of this work is to study the crystal structure of Yb-doped barium cerate solid solution at different Zr concentrat...

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Published in:Solid State Phenomena
Main Author: Nafisah O.; Nurul Waheeda M.; Oskar Hasdinor H.; Zakiah M.
Format: Conference paper
Language:English
Published: Trans Tech Publications Ltd 2021
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85120525900&doi=10.4028%2fwww.scientific.net%2fSSP.317.412&partnerID=40&md5=f58934374ca474e1f9a2b982b40682f5
id 2-s2.0-85120525900
spelling 2-s2.0-85120525900
Nafisah O.; Nurul Waheeda M.; Oskar Hasdinor H.; Zakiah M.
The impact of zr substitution on the crystal structure of yb doped baceo3 solid solution prepared by a sol-gel method
2021
Solid State Phenomena
317 SSP

10.4028/www.scientific.net/SSP.317.412
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85120525900&doi=10.4028%2fwww.scientific.net%2fSSP.317.412&partnerID=40&md5=f58934374ca474e1f9a2b982b40682f5
A modified sol-gel method using metal nitrate salts was adopted to synthesis proton conductor of Ba(Ce1-xZrx)0.95Yb0.05O2.975 where x=0.2, 0.3, 0.4, 0.5 and 0.6 ceramic powders. The aim of this work is to study the crystal structure of Yb-doped barium cerate solid solution at different Zr concentrations. The powder was calcined at 1100°C for 12 hours and pressed at 5 tons to become a pellet by a dry pressing technique. The pellet was sintered at 1400°C in air for 6 hours and ground to powder form prior to the X-ray diffraction measurement. The raw diffraction data of the sample at room temperature was analyzed using Rietveld refinement method in X’pert Highscore software. Cubic crystal structure was observed by software with goodness of fit in average 2.82. Phase formation, structure analysis and the empirical rule which holds the linear relation between lattice parameters at different Zr concentrations using Vegard’s Law were also presented and discussed. © 2021 Trans Tech Publications Ltd, Switzerland.
Trans Tech Publications Ltd
10120394
English
Conference paper
author Nafisah O.; Nurul Waheeda M.; Oskar Hasdinor H.; Zakiah M.
spellingShingle Nafisah O.; Nurul Waheeda M.; Oskar Hasdinor H.; Zakiah M.
The impact of zr substitution on the crystal structure of yb doped baceo3 solid solution prepared by a sol-gel method
author_facet Nafisah O.; Nurul Waheeda M.; Oskar Hasdinor H.; Zakiah M.
author_sort Nafisah O.; Nurul Waheeda M.; Oskar Hasdinor H.; Zakiah M.
title The impact of zr substitution on the crystal structure of yb doped baceo3 solid solution prepared by a sol-gel method
title_short The impact of zr substitution on the crystal structure of yb doped baceo3 solid solution prepared by a sol-gel method
title_full The impact of zr substitution on the crystal structure of yb doped baceo3 solid solution prepared by a sol-gel method
title_fullStr The impact of zr substitution on the crystal structure of yb doped baceo3 solid solution prepared by a sol-gel method
title_full_unstemmed The impact of zr substitution on the crystal structure of yb doped baceo3 solid solution prepared by a sol-gel method
title_sort The impact of zr substitution on the crystal structure of yb doped baceo3 solid solution prepared by a sol-gel method
publishDate 2021
container_title Solid State Phenomena
container_volume 317 SSP
container_issue
doi_str_mv 10.4028/www.scientific.net/SSP.317.412
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85120525900&doi=10.4028%2fwww.scientific.net%2fSSP.317.412&partnerID=40&md5=f58934374ca474e1f9a2b982b40682f5
description A modified sol-gel method using metal nitrate salts was adopted to synthesis proton conductor of Ba(Ce1-xZrx)0.95Yb0.05O2.975 where x=0.2, 0.3, 0.4, 0.5 and 0.6 ceramic powders. The aim of this work is to study the crystal structure of Yb-doped barium cerate solid solution at different Zr concentrations. The powder was calcined at 1100°C for 12 hours and pressed at 5 tons to become a pellet by a dry pressing technique. The pellet was sintered at 1400°C in air for 6 hours and ground to powder form prior to the X-ray diffraction measurement. The raw diffraction data of the sample at room temperature was analyzed using Rietveld refinement method in X’pert Highscore software. Cubic crystal structure was observed by software with goodness of fit in average 2.82. Phase formation, structure analysis and the empirical rule which holds the linear relation between lattice parameters at different Zr concentrations using Vegard’s Law were also presented and discussed. © 2021 Trans Tech Publications Ltd, Switzerland.
publisher Trans Tech Publications Ltd
issn 10120394
language English
format Conference paper
accesstype
record_format scopus
collection Scopus
_version_ 1809678028000722944

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