Comparative corrosion behaviour of austenitic 316L and duplex 2205 stainless steels: microstructure and property evolution at highly partial pressure of H2S
This study extensively compares the corrosion behavior of austenitic 316L and Duplex 2205 stainless-steels at different partial pressures of H2S gases. The results showed that the corrosion rate of both steels at 3 bar H2S showed the highest rate among those parameter setups. 316L steel is dominated...
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Taylor and Francis Ltd.
2022
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2-s2.0-85115231169 Shah M.; Ayob M.T.M.; Yaakob N.; Embong Z.; Othman N.K. Comparative corrosion behaviour of austenitic 316L and duplex 2205 stainless steels: microstructure and property evolution at highly partial pressure of H2S 2022 Corrosion Engineering Science and Technology 57 1 10.1080/1478422X.2021.1980647 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85115231169&doi=10.1080%2f1478422X.2021.1980647&partnerID=40&md5=c9b512001f3a3f4d67224325e6a59b00 This study extensively compares the corrosion behavior of austenitic 316L and Duplex 2205 stainless-steels at different partial pressures of H2S gases. The results showed that the corrosion rate of both steels at 3 bar H2S showed the highest rate among those parameter setups. 316L steel is dominated by both uniform and pitting corrosion under H2S-containing conditions due to the dissolution of Cr present on the alloy surface. According to the cross-sectional analysis, a Cr enrichment layer formed at 0 bar H2S in both steels. After depletion of the Cr compound in the passive film of both steels, Ni was enriched in the outer layer at 3 bar H2S, forming Ni oxide/sulphide compounds within the passive layer. At 15 bar H2S, Mo was enriched in 316L steel, while Fe and Cr were enriched on the 2205 steel surface. Thus, a kinetic study of the chemical composition of both steels was discussed. © 2021 Institute of Materials, Minerals and Mining Published by Taylor & Francis on behalf of the Institute. Taylor and Francis Ltd. 1478422X English Article |
author |
Shah M.; Ayob M.T.M.; Yaakob N.; Embong Z.; Othman N.K. |
spellingShingle |
Shah M.; Ayob M.T.M.; Yaakob N.; Embong Z.; Othman N.K. Comparative corrosion behaviour of austenitic 316L and duplex 2205 stainless steels: microstructure and property evolution at highly partial pressure of H2S |
author_facet |
Shah M.; Ayob M.T.M.; Yaakob N.; Embong Z.; Othman N.K. |
author_sort |
Shah M.; Ayob M.T.M.; Yaakob N.; Embong Z.; Othman N.K. |
title |
Comparative corrosion behaviour of austenitic 316L and duplex 2205 stainless steels: microstructure and property evolution at highly partial pressure of H2S |
title_short |
Comparative corrosion behaviour of austenitic 316L and duplex 2205 stainless steels: microstructure and property evolution at highly partial pressure of H2S |
title_full |
Comparative corrosion behaviour of austenitic 316L and duplex 2205 stainless steels: microstructure and property evolution at highly partial pressure of H2S |
title_fullStr |
Comparative corrosion behaviour of austenitic 316L and duplex 2205 stainless steels: microstructure and property evolution at highly partial pressure of H2S |
title_full_unstemmed |
Comparative corrosion behaviour of austenitic 316L and duplex 2205 stainless steels: microstructure and property evolution at highly partial pressure of H2S |
title_sort |
Comparative corrosion behaviour of austenitic 316L and duplex 2205 stainless steels: microstructure and property evolution at highly partial pressure of H2S |
publishDate |
2022 |
container_title |
Corrosion Engineering Science and Technology |
container_volume |
57 |
container_issue |
1 |
doi_str_mv |
10.1080/1478422X.2021.1980647 |
url |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85115231169&doi=10.1080%2f1478422X.2021.1980647&partnerID=40&md5=c9b512001f3a3f4d67224325e6a59b00 |
description |
This study extensively compares the corrosion behavior of austenitic 316L and Duplex 2205 stainless-steels at different partial pressures of H2S gases. The results showed that the corrosion rate of both steels at 3 bar H2S showed the highest rate among those parameter setups. 316L steel is dominated by both uniform and pitting corrosion under H2S-containing conditions due to the dissolution of Cr present on the alloy surface. According to the cross-sectional analysis, a Cr enrichment layer formed at 0 bar H2S in both steels. After depletion of the Cr compound in the passive film of both steels, Ni was enriched in the outer layer at 3 bar H2S, forming Ni oxide/sulphide compounds within the passive layer. At 15 bar H2S, Mo was enriched in 316L steel, while Fe and Cr were enriched on the 2205 steel surface. Thus, a kinetic study of the chemical composition of both steels was discussed. © 2021 Institute of Materials, Minerals and Mining Published by Taylor & Francis on behalf of the Institute. |
publisher |
Taylor and Francis Ltd. |
issn |
1478422X |
language |
English |
format |
Article |
accesstype |
|
record_format |
scopus |
collection |
Scopus |
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1809677892829839360 |