Fourier transform infrared (FTIR) authentication and batch-to-batch consistency for different types of paints using benchtop and handheld FTIR spectrophotometers for oil and gas industry

Standardization of Fourier transform infrared (FTIR) fingerprint region for paints and assessment on the reproducibility using different spectrophotometers were investigated. While selective fingerprint regions may be confusing for technicians/analysts who are non-chemists, we attempt to generalize...

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Bibliographic Details
Published in:Polymer Engineering and Science
Main Author: Salim Y.S.; Rashid N.A.; Halim S.I.A.; Chan C.H.; Ong C.H.; Harun M.K.
Format: Article
Language:English
Published: John Wiley and Sons Inc 2021
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85108593727&doi=10.1002%2fpen.25746&partnerID=40&md5=9bc0de95a8c1a802f0ba2f88ed4af23d
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Summary:Standardization of Fourier transform infrared (FTIR) fingerprint region for paints and assessment on the reproducibility using different spectrophotometers were investigated. While selective fingerprint regions may be confusing for technicians/analysts who are non-chemists, we attempt to generalize these regions (e.g., 1300–1000 cm−1 for Epoxy part A and 1400–1000 cm−1 for Epoxy part B) by choosing a universal region (2000–900 cm−1) that works for different paints. Comparison result using a paired student t-test shows that the degree of similarity (r) values from the studied regions are not statistically different. The paint fails the screening analysis occasionally on-site when analyzed using handheld FTIR due to the higher level of noise that gives low r values (r < 0.900 ± 0.002). The same samples were analyzed using a benchtop FTIR and the r values are above 0.900 ± 0.002. While the screening may lead to a false rejection of the sample on-site, there could be occurrence of false acceptance. The on-site screening of EPZ part A with different formulations, for instance, shows that the r values over the entire IR spectrum are above 0.900 ± 0.002 when analyzed using handheld FTIR. After the samples were analyzed using the benchtop, the r values fall below 0.900 ± 0.002. © 2021 Society of Plastics Engineers.
ISSN:323888
DOI:10.1002/pen.25746