Biosorption of methylene blue dye by rice (Oryza sativa L.) straw: Adsorption and mechanism study

• Published in: Desalination and Water Treatment
• Main Author: Jawad A.H.; Hum N.N.M.F.; Farhan A.M.; Mastuli M.S.
• Format: Article
• Language: English
• Published: Desalination Publications 2020
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85098987122&doi=10.5004%2fdwt.2020.25644&partnerID=40&md5=746e58b86d5495ad2cd0b1881383c5a7

In this work, rice (Oryza sativa L.) straw biosorbent (RSB) was evaluated as natural, renewable, and low-cost biosorbent for removal of methylene blue (MB) dye from aqueous solution. The structural characterization of the RSB was performed through pore structural analysis (Brunauer–Emmett– Teller), scanning electron microscopy and energy dispersive X-ray analysis, X-ray diffraction, Fourier transform infrared, point of zero charge method, and proximate analysis. Batch adsorption experiments were conducted to study the influence of adsorbent dosage (0.05–0.30 g), solution pH (2–12), initial dye concentration (20–100 mg/L), and contact time (0–240 min) on the adsorption of the MB. The kinetic uptake results were well described by the pseudo-second-order kinetic. The experimental data at equilibrium fitted well with the Langmuir model at 303°K, and the maximum adsorp-tion capacity of MB on the RSB surface was found to be 158 mg/g. The mechanism of adsorption included mainly electrostatic attractions, n–π stacking interaction, and hydrogen bonding interac-tion. The results indicate the potential use of RBS as natural, renewable, and low-cost biosorbent for the removal of MB dye as a model of cationic dye. © 2020 Desalination Publications. All rights reserved.