Summary: | This work studied and compared the tribocorrosion behaviour of low temperature nitridedaustenitic (316L) and duplex (2205) stainless steels. After gaseous nitriding at 450 °C for10 h, the S-phase layer formed on the duplex stainless steel is thicker and harder than that onthe austenitic stainless steel. The formation of S-phase layers reduces both mechanical wearand chemical wear of stainless steels but the duplex type exhibits better tribocorrosion performance. Wearing through of the S-phase layer during tribocorrosion leads to asignificant drop in open circuit potential, friction instability, and total material loss from the nitrided specimens. The work concludes that low temperature gaseous nitriding is effective in improving the tribocorrosion behaviour of these materials to avoiding catastrophic surface failures. © 2020 Elsevier Ltd
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