Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil
Epoxidized oleic acid is often regarded as a high value oleochemical due to the wide range of industrial applications including cosmetics, personal care and pharmaceutical products. Epoxidized oleic acid also extensively chosen by industry due to its advantages on the good performance as intermediat...
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Institute of Physics Publishing
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2-s2.0-85068902804 Jalil M.J.; Md Zaini M.S.; Mohd Yamin A.F.; Azmi I.S.; Chang S.H.; Morad N.; Hadi A. Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil 2019 IOP Conference Series: Earth and Environmental Science 291 1 10.1088/1755-1315/291/1/012046 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85068902804&doi=10.1088%2f1755-1315%2f291%2f1%2f012046&partnerID=40&md5=1edf757b9f83d06a29a242c37e2a3341 Epoxidized oleic acid is often regarded as a high value oleochemical due to the wide range of industrial applications including cosmetics, personal care and pharmaceutical products. Epoxidized oleic acid also extensively chosen by industry due to its advantages on the good performance as intermediate chemicals and can be obtained from renewable sources. Synthesis and physicochemical properties of oleic acid palm oil was analyzed for further reaction of epoxidation. In this study, the epoxidation of oleic acid was investigated with performic acid generated in situ from hydrogen peroxide in H2O2 (30%) with formic acid. The characterization of oleic acid through iodine value, viscosity, acid value, saponification number and refractive index were 130, 146. 190.0, 206.1 and 1.47 respectively. On the other hand, the characterization of epoxidized oleic acid were 109.8, 156, 192.6, 219.9 and 1.38 of the same analysis. The chemical structures of the products were confirmed by 1H-NMR and 13C-NMR spectral analysis. © 2019 Published under licence by IOP Publishing Ltd. Institute of Physics Publishing 17551307 English Conference paper All Open Access; Gold Open Access |
author |
Jalil M.J.; Md Zaini M.S.; Mohd Yamin A.F.; Azmi I.S.; Chang S.H.; Morad N.; Hadi A. |
spellingShingle |
Jalil M.J.; Md Zaini M.S.; Mohd Yamin A.F.; Azmi I.S.; Chang S.H.; Morad N.; Hadi A. Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil |
author_facet |
Jalil M.J.; Md Zaini M.S.; Mohd Yamin A.F.; Azmi I.S.; Chang S.H.; Morad N.; Hadi A. |
author_sort |
Jalil M.J.; Md Zaini M.S.; Mohd Yamin A.F.; Azmi I.S.; Chang S.H.; Morad N.; Hadi A. |
title |
Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil |
title_short |
Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil |
title_full |
Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil |
title_fullStr |
Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil |
title_full_unstemmed |
Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil |
title_sort |
Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil |
publishDate |
2019 |
container_title |
IOP Conference Series: Earth and Environmental Science |
container_volume |
291 |
container_issue |
1 |
doi_str_mv |
10.1088/1755-1315/291/1/012046 |
url |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85068902804&doi=10.1088%2f1755-1315%2f291%2f1%2f012046&partnerID=40&md5=1edf757b9f83d06a29a242c37e2a3341 |
description |
Epoxidized oleic acid is often regarded as a high value oleochemical due to the wide range of industrial applications including cosmetics, personal care and pharmaceutical products. Epoxidized oleic acid also extensively chosen by industry due to its advantages on the good performance as intermediate chemicals and can be obtained from renewable sources. Synthesis and physicochemical properties of oleic acid palm oil was analyzed for further reaction of epoxidation. In this study, the epoxidation of oleic acid was investigated with performic acid generated in situ from hydrogen peroxide in H2O2 (30%) with formic acid. The characterization of oleic acid through iodine value, viscosity, acid value, saponification number and refractive index were 130, 146. 190.0, 206.1 and 1.47 respectively. On the other hand, the characterization of epoxidized oleic acid were 109.8, 156, 192.6, 219.9 and 1.38 of the same analysis. The chemical structures of the products were confirmed by 1H-NMR and 13C-NMR spectral analysis. © 2019 Published under licence by IOP Publishing Ltd. |
publisher |
Institute of Physics Publishing |
issn |
17551307 |
language |
English |
format |
Conference paper |
accesstype |
All Open Access; Gold Open Access |
record_format |
scopus |
collection |
Scopus |
_version_ |
1809677905996808192 |