Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil

Epoxidized oleic acid is often regarded as a high value oleochemical due to the wide range of industrial applications including cosmetics, personal care and pharmaceutical products. Epoxidized oleic acid also extensively chosen by industry due to its advantages on the good performance as intermediat...

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Published in:IOP Conference Series: Earth and Environmental Science
Main Author: Jalil M.J.; Md Zaini M.S.; Mohd Yamin A.F.; Azmi I.S.; Chang S.H.; Morad N.; Hadi A.
Format: Conference paper
Language:English
Published: Institute of Physics Publishing 2019
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85068902804&doi=10.1088%2f1755-1315%2f291%2f1%2f012046&partnerID=40&md5=1edf757b9f83d06a29a242c37e2a3341
id 2-s2.0-85068902804
spelling 2-s2.0-85068902804
Jalil M.J.; Md Zaini M.S.; Mohd Yamin A.F.; Azmi I.S.; Chang S.H.; Morad N.; Hadi A.
Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil
2019
IOP Conference Series: Earth and Environmental Science
291
1
10.1088/1755-1315/291/1/012046
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85068902804&doi=10.1088%2f1755-1315%2f291%2f1%2f012046&partnerID=40&md5=1edf757b9f83d06a29a242c37e2a3341
Epoxidized oleic acid is often regarded as a high value oleochemical due to the wide range of industrial applications including cosmetics, personal care and pharmaceutical products. Epoxidized oleic acid also extensively chosen by industry due to its advantages on the good performance as intermediate chemicals and can be obtained from renewable sources. Synthesis and physicochemical properties of oleic acid palm oil was analyzed for further reaction of epoxidation. In this study, the epoxidation of oleic acid was investigated with performic acid generated in situ from hydrogen peroxide in H2O2 (30%) with formic acid. The characterization of oleic acid through iodine value, viscosity, acid value, saponification number and refractive index were 130, 146. 190.0, 206.1 and 1.47 respectively. On the other hand, the characterization of epoxidized oleic acid were 109.8, 156, 192.6, 219.9 and 1.38 of the same analysis. The chemical structures of the products were confirmed by 1H-NMR and 13C-NMR spectral analysis. © 2019 Published under licence by IOP Publishing Ltd.
Institute of Physics Publishing
17551307
English
Conference paper
All Open Access; Gold Open Access
author Jalil M.J.; Md Zaini M.S.; Mohd Yamin A.F.; Azmi I.S.; Chang S.H.; Morad N.; Hadi A.
spellingShingle Jalil M.J.; Md Zaini M.S.; Mohd Yamin A.F.; Azmi I.S.; Chang S.H.; Morad N.; Hadi A.
Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil
author_facet Jalil M.J.; Md Zaini M.S.; Mohd Yamin A.F.; Azmi I.S.; Chang S.H.; Morad N.; Hadi A.
author_sort Jalil M.J.; Md Zaini M.S.; Mohd Yamin A.F.; Azmi I.S.; Chang S.H.; Morad N.; Hadi A.
title Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil
title_short Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil
title_full Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil
title_fullStr Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil
title_full_unstemmed Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil
title_sort Synthesis and physicochemical properties of epoxidized oleic acid-based palm oil
publishDate 2019
container_title IOP Conference Series: Earth and Environmental Science
container_volume 291
container_issue 1
doi_str_mv 10.1088/1755-1315/291/1/012046
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85068902804&doi=10.1088%2f1755-1315%2f291%2f1%2f012046&partnerID=40&md5=1edf757b9f83d06a29a242c37e2a3341
description Epoxidized oleic acid is often regarded as a high value oleochemical due to the wide range of industrial applications including cosmetics, personal care and pharmaceutical products. Epoxidized oleic acid also extensively chosen by industry due to its advantages on the good performance as intermediate chemicals and can be obtained from renewable sources. Synthesis and physicochemical properties of oleic acid palm oil was analyzed for further reaction of epoxidation. In this study, the epoxidation of oleic acid was investigated with performic acid generated in situ from hydrogen peroxide in H2O2 (30%) with formic acid. The characterization of oleic acid through iodine value, viscosity, acid value, saponification number and refractive index were 130, 146. 190.0, 206.1 and 1.47 respectively. On the other hand, the characterization of epoxidized oleic acid were 109.8, 156, 192.6, 219.9 and 1.38 of the same analysis. The chemical structures of the products were confirmed by 1H-NMR and 13C-NMR spectral analysis. © 2019 Published under licence by IOP Publishing Ltd.
publisher Institute of Physics Publishing
issn 17551307
language English
format Conference paper
accesstype All Open Access; Gold Open Access
record_format scopus
collection Scopus
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