Crystal structure of bis(2-methoxy-6-((Z)-(p-tolylimino)methyl)phenoxy)palladium
The structure of bis(2-methoxy-6-((Z)-(p-tolylimino)methyl)phenoxy)palladium crystallized in a monoclinic system and was characterized thus: P21/c, a = 13.0221(14), b = 11.6615(13), c = 8.4898(9)Å, β = 97.327(4)°, Z = 2, V = 1278.7(2)Å3. The crystal structure was solved by direct methods and refined...
| Published in: | X-ray Structure Analysis Online |
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| Main Author: | |
| Format: | Article |
| Language: | English |
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Japan Society for Analytical Chemistry
2019
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85067995139&doi=10.2116%2fxraystruct.35.25&partnerID=40&md5=af883d0889e577721402ed1173f7b1ca |
| Summary: | The structure of bis(2-methoxy-6-((Z)-(p-tolylimino)methyl)phenoxy)palladium crystallized in a monoclinic system and was characterized thus: P21/c, a = 13.0221(14), b = 11.6615(13), c = 8.4898(9)Å, β = 97.327(4)°, Z = 2, V = 1278.7(2)Å3. The crystal structure was solved by direct methods and refined by full-matrix least-squares on F2 to final values of R1 = 0.0349 [I > 2σ(I)] and wR2 = 0.0824. The molecules have two-fold symmetry about the centre Pd1 atom. Two ligands were coordinated to the Pd1 atom via oxygen and nitrogen atoms in a bidentate manner to form a square-planar geometrical structure. © 2019, The Japan Society for Analytical Chemistry. |
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| ISSN: | 18833578 |
| DOI: | 10.2116/xraystruct.35.25 |