Synthesis, structural, density functional theory, and X-ray diffraction study of Zn(II) N-isopropylbenzyldithiocarbamate: Anti-corrosion screening in acid media

• Published in: Indonesian Journal of Chemistry
• Main Author: Latif N.S.H.; Ghazali S.A.I.S.M.; Abdullah E.N.; Lahuri A.H.; Ngatiman M.F.; Dzulkifli N.N.
• Format: Article
• Language: English
• Published: Gadjah Mada University 2018
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85059614335&doi=10.22146%2fijc.34703&partnerID=40&md5=b7c7cd558f37874b6246257cae2250ef

Corrosion of metal is a serious issue across many industries and is considered costly. Acids used during the cleaning process in industries may contribute to metal erosion. Dithiocarbamate is a ligand that can act as a corrosion inhibitor due to the presence of sulfur and nitrogen as electronegative atoms. Zn(II) N-isopropylbenzyldithiocarbamate (Zn[N-isopbenzdtc]2) complex was synthesized through direct synthetic method of < 4 °C and characterized using Fourier Transform Infrared-Attenuated Total Reflectance (FTIR-ATR), Ultraviolet-Visible (UV-Vis), Nuclear Magnetic Resonance (NMR), X-ray crystallography study, molar conductivity, melting point, and gravimetric analysis. Corrosion inhibition of mild steel was studied for different corrosive media (1 M HCl and 1 M H2SO4). The synthesized inhibitor was studied at different concentrations of 1, 2, 3, 4, and 5 mM at 40 °C. As a conclusion, as the inhibitor concentration decreased, the efficiency of the corrosion inhibitor also decreased at a constant temperature. In this study, it showed that the corrosion activity of mild steel in 1 M H2SO4 was higher compared to 1 M HCl due to the higher concentration of H+, which makes H2SO4 more corrosive than HCl. © 2018, Gadjah Mada University. All rights reserved.