Functionalization of polyacrylonitrile-grafted cellulose with amidoxime and its antimicrobial property

Copolymer of polyacrylonitrile grafted with cellulose (AN-g-cellulose) was modified by reacting with hydroxylamine hydrochloride at pH 6, to functionalize it with amidoxime functional groups. Fourier Transform Infrared (FTIR) spectroscopy analysis was carried out to characterize the AN-g-cellulose t...

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Bibliographic Details
Published in:AIP Conference Proceedings
Main Author: Abdullah M.; Majid R.A.; Abdullah L.C.; Abdul-Wahab M.F.; Aziz M.Q.F.A.; Sabri N.H.M.; Hamdan S.A.; Zaiton S.N.A.; Muhamad S.H.A.
Format: Conference paper
Language:English
Published: American Institute of Physics Inc. 2018
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85058678851&doi=10.1063%2f1.5080855&partnerID=40&md5=867a20191120a4b5b8d3fe179dd27ea5
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Summary:Copolymer of polyacrylonitrile grafted with cellulose (AN-g-cellulose) was modified by reacting with hydroxylamine hydrochloride at pH 6, to functionalize it with amidoxime functional groups. Fourier Transform Infrared (FTIR) spectroscopy analysis was carried out to characterize the AN-g-cellulose to confirm the presence of amidoxime groups. Water swelling characterization has also been conducted to investigate the water absorptivity of the modified cellulose polymers. The antimicrobial activity was tested against a Gram positive bacteria Staphylococcus aureus and a Gram negative bacteria Pseudomonas aeruginosa. Most of the modified polymers do not seem to inhibit microbial growth, except for AN-g-cellulose on S. aureus, suggesting the need for further modifications and functionalizations to improve the antimicrobial properties. © 2018 Author(s).
ISSN:0094243X
DOI:10.1063/1.5080855