The effect of monomer types and loading on the characterization and absorption of superabsorbent polymer based on waste polystyrene foam

Acrylic acid, polyacrylamide and poly(methyl acrylate)) and waste polystyrene foam via chain growth polymerization technique in the presence of Potassium Persulphate as redox initiator, N,N'-Methylenebisacrylamide as crosslinker and Sorbitane Monooleate (Span 80) as nonionic surfactant were uti...

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書目詳細資料
發表在:AIP Conference Proceedings
主要作者: Mohamed N.R.; Othman N.; Shaari H.A.H.; Jamal S.N.; Majid N.A.; Samsudin D.; Ismail S.N.S.; Hashim F.; Yasin S.B.M.
格式: Conference paper
語言:English
出版: American Institute of Physics Inc. 2018
在線閱讀:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85050509081&doi=10.1063%2f1.5047177&partnerID=40&md5=adcb8a7e174fdc42d55c6b7c9058a950
實物特徵
總結:Acrylic acid, polyacrylamide and poly(methyl acrylate)) and waste polystyrene foam via chain growth polymerization technique in the presence of Potassium Persulphate as redox initiator, N,N'-Methylenebisacrylamide as crosslinker and Sorbitane Monooleate (Span 80) as nonionic surfactant were utilized. In this project, hydrogels based on acrylic acid (AA), acrylamide (AAm) and methyl acrylate (MA) were grafted with waste polystyrene foam (WPSF). The effect of monomer types and ratios of absorption and swelling equilibrium in distilled water was investigated. This is followed by an analysis of hydrogels absorption in saline water and urea solution as well as Fourier Transform Infrared (FTIR) characterization. In swelling studies, hydrogel based on WPSF-graft-acrylic acid showed an ultimate absorption at 6:1 mass ratio of acrylic acid to waste polystyrene foam. Meanwhile, hydrogel based on WPSF-graft-acrylamide and WPSF-graft-methyl acrylate, both showed continuous increased in water uptake with increasing monomer content. Upon characterization with FTIR, a significant hydrophilic functional groups exist in the spectrum that corresponds to the acrylate monomer, WPSF and crosslinker unit. © 2018 Author(s).
ISSN:0094243X
DOI:10.1063/1.5047177