Electrochemical properties of polymer electrolytes treated with 6PPD on 30% poly(Methyl methacrylate) grafted natural rubber; [Sifat elektrokimia elektrolit polimer 30% poli(Metil metakrilat) cangkutan getah asli terawat dengan 6PPD]
30% poly(methyl methacrylate) grafted natural rubber was treated with N-(1,3-dimethylbutyl)-N’-phenyl-p-phenylenediamine (6PPD) additive (TMG30) to retard its degradation before further used as electrolytes. The polymer electrolytes containing MG30-6PPD-LiTF were prepared by solution cast technique....
| Published in: | Malaysian Journal of Analytical Sciences |
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| Main Author: | |
| Format: | Article |
| Language: | English |
| Published: |
Malaysian Society of Analytical Sciences
2018
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85050136388&doi=10.17576%2fmjas-2018-2203-17&partnerID=40&md5=5edbf30d129cf7e7b215c75807096967 |
| Summary: | 30% poly(methyl methacrylate) grafted natural rubber was treated with N-(1,3-dimethylbutyl)-N’-phenyl-p-phenylenediamine (6PPD) additive (TMG30) to retard its degradation before further used as electrolytes. The polymer electrolytes containing MG30-6PPD-LiTF were prepared by solution cast technique. X-ray diffraction studies show the electrolytes with the highest salt content are amorphous in nature. The TMG30-salt complexes were confirmed by using Fourier transformation infrared analysis. The highest ionic conductivity of the TMG30 polymer electrolytes containing 40 wt.% LiTF was found to be 1.5 x 10-2 S/cm at room temperature. Transference number studies show that the sample with highest ionic conductivity exhibits the charge transport species in this TMG30 polymer electrolyte film is predominantly due to ions. © 2018, Malaysian Society of Analytical Sciences. All rights reserved. |
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| ISSN: | 13942506 |
| DOI: | 10.17576/mjas-2018-2203-17 |