Kinetic and thermodynamic of heterogeneously K3PO4/AC-catalysed transesterification via pseudo-first order mechanism and Eyring-Polanyi equation

• Published in: Fuel
• Main Author: Ahmad Farid M.A.; Hassan M.A.; Taufiq-Yap Y.H.; Ibrahim M.L.; Hasan M.Y.; Ali A.A.M.; Othman M.R.; Shirai Y.
• Format: Article
• Language: English
• Published: Elsevier Ltd 2018
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85048270395&doi=10.1016%2fj.fuel.2018.06.029&partnerID=40&md5=d68ebe0fcfd7b96b9ca5af665308930f

The use of carbon-based catalysts has drawn so much interest in biodiesel production due to improved reaction performance. However, there was lack of comprehensive studies in term of its kinetic and thermodynamic perspective. Therefore, a methodical study is essential to uncover the influence of the carbon catalyst with respect to reaction rate and yield. This study represents kinetic and thermodynamic of heterogeneously K3PO4/AC-catalysed transesterification. It was done correspondingly via pseudo-first order mechanism and Eyring-Polanyi equation, whereby, under the optimal reaction temperature of 333.15 K, all data have fitted satisfactorily in both models with resulted R2 of 0.99, respectively. Activation energy (Ea) and Gibbs free energy (ΔG) were calculated as 34.2 kJ mol−1 and −33.68 kJ mol−1, indicating the reaction was exergonic and spontaneous at high temperature. © 2018 Elsevier Ltd