Crystal structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))- bis(methanylylidene))bis(4-methoxyphenol)palladium(II)

Crystal structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))- bis(methanylylidene))bis(4-methoxyphenol)palladium(II)

The structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))bis(methanylylidene))bis(4-methoxyphenol)- palladium(II) was determined by X-ray crystallography analysis. It crystallizes in the space group P21/n, with cell parameter a = 12.5115(7)Å, b = 10.5337(6)Å, c = 15.0080(9)Å, β...

Full description

Bibliographic Details
Published in:X-ray Structure Analysis Online
Main Author: Ahmad S.N.; Bahron H.; Tajuddin A.M.; Sukeri M.M.Y.
Format: Article
Language:English
Published: Japan Society for Analytical Chemistry 2017
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85037692929&doi=10.2116%2fxraystruct.33.73&partnerID=40&md5=a9b2c03cb376c96ca7cbef3a241b7acc
id 2-s2.0-85037692929
spelling 2-s2.0-85037692929
Ahmad S.N.; Bahron H.; Tajuddin A.M.; Sukeri M.M.Y.
Crystal structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))- bis(methanylylidene))bis(4-methoxyphenol)palladium(II)
2017
X-ray Structure Analysis Online
33
12
10.2116/xraystruct.33.73
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85037692929&doi=10.2116%2fxraystruct.33.73&partnerID=40&md5=a9b2c03cb376c96ca7cbef3a241b7acc
The structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))bis(methanylylidene))bis(4-methoxyphenol)- palladium(II) was determined by X-ray crystallography analysis. It crystallizes in the space group P21/n, with cell parameter a = 12.5115(7)Å, b = 10.5337(6)Å, c = 15.0080(9)Å, β = 94.0547(19)°, Z = 4, and V = 1973.0(2)Å3. The crystal structure was solved by direct methods and refined by full-matrix least-squares on F2 to final values of R1 = 0.0415 and wR2 = 0.1251. The Schiff-base ligand was found to coordinate to the palladium(II) through tetradentate ONNO atoms forming a slightly distorted square-planar complex. Two intermolecular hydrogen bonds, C-H···O, stabilized two molecules forming dimers. © The Japan Society for Analytical Chemistry.
Japan Society for Analytical Chemistry
18833578
English
Article
All Open Access; Gold Open Access
author Ahmad S.N.; Bahron H.; Tajuddin A.M.; Sukeri M.M.Y.
spellingShingle Ahmad S.N.; Bahron H.; Tajuddin A.M.; Sukeri M.M.Y.
Crystal structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))- bis(methanylylidene))bis(4-methoxyphenol)palladium(II)
author_facet Ahmad S.N.; Bahron H.; Tajuddin A.M.; Sukeri M.M.Y.
author_sort Ahmad S.N.; Bahron H.; Tajuddin A.M.; Sukeri M.M.Y.
title Crystal structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))- bis(methanylylidene))bis(4-methoxyphenol)palladium(II)
title_short Crystal structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))- bis(methanylylidene))bis(4-methoxyphenol)palladium(II)
title_full Crystal structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))- bis(methanylylidene))bis(4-methoxyphenol)palladium(II)
title_fullStr Crystal structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))- bis(methanylylidene))bis(4-methoxyphenol)palladium(II)
title_full_unstemmed Crystal structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))- bis(methanylylidene))bis(4-methoxyphenol)palladium(II)
title_sort Crystal structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))- bis(methanylylidene))bis(4-methoxyphenol)palladium(II)
publishDate 2017
container_title X-ray Structure Analysis Online
container_volume 33
container_issue 12
doi_str_mv 10.2116/xraystruct.33.73
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85037692929&doi=10.2116%2fxraystruct.33.73&partnerID=40&md5=a9b2c03cb376c96ca7cbef3a241b7acc
description The structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))bis(methanylylidene))bis(4-methoxyphenol)- palladium(II) was determined by X-ray crystallography analysis. It crystallizes in the space group P21/n, with cell parameter a = 12.5115(7)Å, b = 10.5337(6)Å, c = 15.0080(9)Å, β = 94.0547(19)°, Z = 4, and V = 1973.0(2)Å3. The crystal structure was solved by direct methods and refined by full-matrix least-squares on F2 to final values of R1 = 0.0415 and wR2 = 0.1251. The Schiff-base ligand was found to coordinate to the palladium(II) through tetradentate ONNO atoms forming a slightly distorted square-planar complex. Two intermolecular hydrogen bonds, C-H···O, stabilized two molecules forming dimers. © The Japan Society for Analytical Chemistry.
publisher Japan Society for Analytical Chemistry
issn 18833578
language English
format Article
accesstype All Open Access; Gold Open Access
record_format scopus
collection Scopus
_version_ 1809677909056552960

Similar Items