Crystal structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))- bis(methanylylidene))bis(4-methoxyphenol)palladium(II)
The structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))bis(methanylylidene))bis(4-methoxyphenol)- palladium(II) was determined by X-ray crystallography analysis. It crystallizes in the space group P21/n, with cell parameter a = 12.5115(7)Å, b = 10.5337(6)Å, c = 15.0080(9)Å, β...
| Published in: | X-ray Structure Analysis Online |
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| Main Author: | |
| Format: | Article |
| Language: | English |
| Published: |
Japan Society for Analytical Chemistry
2017
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85037692929&doi=10.2116%2fxraystruct.33.73&partnerID=40&md5=a9b2c03cb376c96ca7cbef3a241b7acc |
| Summary: | The structure of 2,2'-(((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))bis(methanylylidene))bis(4-methoxyphenol)- palladium(II) was determined by X-ray crystallography analysis. It crystallizes in the space group P21/n, with cell parameter a = 12.5115(7)Å, b = 10.5337(6)Å, c = 15.0080(9)Å, β = 94.0547(19)°, Z = 4, and V = 1973.0(2)Å3. The crystal structure was solved by direct methods and refined by full-matrix least-squares on F2 to final values of R1 = 0.0415 and wR2 = 0.1251. The Schiff-base ligand was found to coordinate to the palladium(II) through tetradentate ONNO atoms forming a slightly distorted square-planar complex. Two intermolecular hydrogen bonds, C-H···O, stabilized two molecules forming dimers. © The Japan Society for Analytical Chemistry. |
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| ISSN: | 18833578 |
| DOI: | 10.2116/xraystruct.33.73 |