Sodium ion conducting NaI-Na3PO4 solid electrolyte with PLLTMEDA as an additive for solid state batteries
In this work poly(L-leucine)1,3-diamino propane (PLLTMEDA) has been chosen as an additive to the binary compound sodium iodide (NaI) and sodium phosphate (Na3PO4). A small amount of PLLTMEDA was added to the optimum composition of the binary compound (0.5 NaI-0.5 Na3PO4). Results from EIS have prove...
| Published in: | International Journal of Nanotechnology |
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| Format: | Article |
| Language: | English |
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Inderscience Publishers
2017
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85014083184&doi=10.1504%2fIJNT.2017.082450&partnerID=40&md5=a44d50c627a10b777c77594ace9bf143 |
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2-s2.0-85014083184 Ahmad A.H.; Hassan N. Sodium ion conducting NaI-Na3PO4 solid electrolyte with PLLTMEDA as an additive for solid state batteries 2017 International Journal of Nanotechnology 14 1-Jun 10.1504/IJNT.2017.082450 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85014083184&doi=10.1504%2fIJNT.2017.082450&partnerID=40&md5=a44d50c627a10b777c77594ace9bf143 In this work poly(L-leucine)1,3-diamino propane (PLLTMEDA) has been chosen as an additive to the binary compound sodium iodide (NaI) and sodium phosphate (Na3PO4). A small amount of PLLTMEDA was added to the optimum composition of the binary compound (0.5 NaI-0.5 Na3PO4). Results from EIS have proven this new compound is superionic with maximum conductivity of 1.12 × 10-3 S cm-1. Fourier transform infrared spectroscopy (FTIR) analysis revealed the band of C=O at 1650 cm-1 experienced a shift, indicating that some interaction had occurred. The ionic transference number was found to be ≈1 for the optimum composition with maximum conductivity which suggests that the sample is ionic in nature. The optimum composition of the sample was used as solid electrolyte in solid state sodium battery. The sodium battery was tested by the discharged characteristic at a current of ≈1.0 μA. The solid state sodium batteries exhibited a discharge capacity of 173 mAh/g. Copyright © 2017 Inderscience Enterprises Ltd. Inderscience Publishers 14757435 English Article |
| author |
Ahmad A.H.; Hassan N. |
| spellingShingle |
Ahmad A.H.; Hassan N. Sodium ion conducting NaI-Na3PO4 solid electrolyte with PLLTMEDA as an additive for solid state batteries |
| author_facet |
Ahmad A.H.; Hassan N. |
| author_sort |
Ahmad A.H.; Hassan N. |
| title |
Sodium ion conducting NaI-Na3PO4 solid electrolyte with PLLTMEDA as an additive for solid state batteries |
| title_short |
Sodium ion conducting NaI-Na3PO4 solid electrolyte with PLLTMEDA as an additive for solid state batteries |
| title_full |
Sodium ion conducting NaI-Na3PO4 solid electrolyte with PLLTMEDA as an additive for solid state batteries |
| title_fullStr |
Sodium ion conducting NaI-Na3PO4 solid electrolyte with PLLTMEDA as an additive for solid state batteries |
| title_full_unstemmed |
Sodium ion conducting NaI-Na3PO4 solid electrolyte with PLLTMEDA as an additive for solid state batteries |
| title_sort |
Sodium ion conducting NaI-Na3PO4 solid electrolyte with PLLTMEDA as an additive for solid state batteries |
| publishDate |
2017 |
| container_title |
International Journal of Nanotechnology |
| container_volume |
14 |
| container_issue |
1-Jun |
| doi_str_mv |
10.1504/IJNT.2017.082450 |
| url |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85014083184&doi=10.1504%2fIJNT.2017.082450&partnerID=40&md5=a44d50c627a10b777c77594ace9bf143 |
| description |
In this work poly(L-leucine)1,3-diamino propane (PLLTMEDA) has been chosen as an additive to the binary compound sodium iodide (NaI) and sodium phosphate (Na3PO4). A small amount of PLLTMEDA was added to the optimum composition of the binary compound (0.5 NaI-0.5 Na3PO4). Results from EIS have proven this new compound is superionic with maximum conductivity of 1.12 × 10-3 S cm-1. Fourier transform infrared spectroscopy (FTIR) analysis revealed the band of C=O at 1650 cm-1 experienced a shift, indicating that some interaction had occurred. The ionic transference number was found to be ≈1 for the optimum composition with maximum conductivity which suggests that the sample is ionic in nature. The optimum composition of the sample was used as solid electrolyte in solid state sodium battery. The sodium battery was tested by the discharged characteristic at a current of ≈1.0 μA. The solid state sodium batteries exhibited a discharge capacity of 173 mAh/g. Copyright © 2017 Inderscience Enterprises Ltd. |
| publisher |
Inderscience Publishers |
| issn |
14757435 |
| language |
English |
| format |
Article |
| accesstype |
|
| record_format |
scopus |
| collection |
Scopus |
| _version_ |
1809678484784545792 |