Structural and functional investigation of graphene oxide-Fe 3 O 4 nanocomposites for the heterogeneous Fenton-like reaction
Graphene oxide-iron oxide (GO-Fe3O4) nanocomposites were synthesised by co-precipitating iron salts onto GO sheets in basic solution. The results showed that formation of two distinct structures was dependent upon the GO loading. The first structure corresponds to a low GO loading up to 10wt%, assoc...
| Published in: | Scientific Reports |
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| Main Author: | |
| Format: | Article |
| Language: | English |
| Published: |
Nature Publishing Group
2014
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84898755987&doi=10.1038%2fsrep04594&partnerID=40&md5=e533c96740856fd33b5f4cb6fdcf518b |
| Summary: | Graphene oxide-iron oxide (GO-Fe3O4) nanocomposites were synthesised by co-precipitating iron salts onto GO sheets in basic solution. The results showed that formation of two distinct structures was dependent upon the GO loading. The first structure corresponds to a low GO loading up to 10wt%, associated with the beneficial intercalation of GO within Fe3O4nanoparticles and resulting in higher surface area up to 409m2g-1. High GO loading beyond 10 wt% led to the aggregation of Fe3O4 nanoparticles and the undesirable stacking of GO sheets. The presence of strong interfacial interactions (Fe-O-C bonds) between both components at low GO loading lead to 20% higher degradation of Acid Orange 7 than the Fe3O4 nanoparticles in heterogeneous Fenton-like reaction. This behaviour was attributed to synergistic structural and functional effect of the combined GO and Fe3O4 nanoparticles. |
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| ISSN: | 20452322 |
| DOI: | 10.1038/srep04594 |