Enhanced activity of Ru/TiO 2 catalyst using bisupport, bentonite-TiO 2 for hydrogenolysis of glycerol in aqueous media

• Published in: Applied Catalysis A: General
• Main Author: Hamzah N.; Nordin N.M.; Nadzri A.H.A.; Nik Y.A.; Kassim M.B.; Yarmo M.A.
• Format: Article
• Language: English
• Published: 2012
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84857922219&doi=10.1016%2fj.apcata.2012.01.020&partnerID=40&md5=93e7c28a9c43fca1d3696cb3384cef7e

A combination of bentonite-TiO 2 was used as support to enhance the activity of Ru/TiO 2 catalyst in hydrogenolysis of aqueous glycerol to 1,2-propanediol. A series of bentonite, TiO 2, SiO 2 and Al 2O 3 supported Ru catalyst were fabricated and characterized by XRD, XPS, BET, FESEM-EDX and TEM to establish some physicochemical properties of the catalysts. The activity of the catalysts was tested in glycerol hydrogenolysis reaction and were found to be in the following increasing order: Ru/SiO 2 < Ru/TiO 2 ≈ Ru/Al 2O 3 < Ru/bentonite. In particular, Ru/bentonite catalyst recorded the highest conversion (62.8%) of glycerol (20 wt%) with 80.1% selectivity to 1,2-pronediol at 150°C, 20-30 bar H 2 with a reaction duration of 7 h. The Ru/TiO 2 catalyst exhibited the highest selectivity (83.7%) for hydrogenolysis of glycerol to 1,2-propanediol and with 38.8% conversion only. The activity of Ru/TiO 2 catalyst was enhanced by adding bentonite to the titania support at 1:2 ratio resulting in an 80% increasing the activity from 38.8% to 69.8% under the same optimum condition for Ru/TiO 2 while maintaining an 80% selectivity to 1,2-propanediol. TPD-NH 3 analysis found that mixed support could increase catalyst acidity. CO pulse chemisorption analysis revealed that Ru particles was well dispersed with the smallest average size particles (1.5 nm) which could contribute to high activity of Ru/TiO 2 catalyst for hydrogenolysis of glycerol. © 2012 Elsevier B.V. All rights reserved.