Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato- κ 2 N,O 1}nickel(II)
In the title compound, [Ni(C 15H 13FNO 2) 2], the Ni II atom is tetra-coordinated by two N atoms and two O atoms from two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth- oxy-phenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni II atom are trans to each other, as t...
| Published in: | Acta Crystallographica Section E: Structure Reports Online |
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| Format: | Article |
| Language: | English |
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2011
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-80051506107&doi=10.1107%2fS1600536811025189&partnerID=40&md5=ad996b41fdf6b277da8cb627fca62cee |
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2-s2.0-80051506107 |
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2-s2.0-80051506107 Bahron H.; Tajuddin A.M.; Ibrahim W.N.W.; Hemamalini M.; Fun H.-K. Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato- κ 2 N,O 1}nickel(II) 2011 Acta Crystallographica Section E: Structure Reports Online 67 8 10.1107/S1600536811025189 https://www.scopus.com/inward/record.uri?eid=2-s2.0-80051506107&doi=10.1107%2fS1600536811025189&partnerID=40&md5=ad996b41fdf6b277da8cb627fca62cee In the title compound, [Ni(C 15H 13FNO 2) 2], the Ni II atom is tetra-coordinated by two N atoms and two O atoms from two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth- oxy-phenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni II atom are trans to each other, as the Ni II atom lies on an inversion centre. In the fluoro-phenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex molecules are linked via inter-molecular C - H⋯F hydrogen bonds, forming chains along [001]. 16005368 English Article All Open Access; Gold Open Access; Green Open Access |
| author |
Bahron H.; Tajuddin A.M.; Ibrahim W.N.W.; Hemamalini M.; Fun H.-K. |
| spellingShingle |
Bahron H.; Tajuddin A.M.; Ibrahim W.N.W.; Hemamalini M.; Fun H.-K. Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato- κ 2 N,O 1}nickel(II) |
| author_facet |
Bahron H.; Tajuddin A.M.; Ibrahim W.N.W.; Hemamalini M.; Fun H.-K. |
| author_sort |
Bahron H.; Tajuddin A.M.; Ibrahim W.N.W.; Hemamalini M.; Fun H.-K. |
| title |
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato- κ 2 N,O 1}nickel(II) |
| title_short |
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato- κ 2 N,O 1}nickel(II) |
| title_full |
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato- κ 2 N,O 1}nickel(II) |
| title_fullStr |
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato- κ 2 N,O 1}nickel(II) |
| title_full_unstemmed |
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato- κ 2 N,O 1}nickel(II) |
| title_sort |
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato- κ 2 N,O 1}nickel(II) |
| publishDate |
2011 |
| container_title |
Acta Crystallographica Section E: Structure Reports Online |
| container_volume |
67 |
| container_issue |
8 |
| doi_str_mv |
10.1107/S1600536811025189 |
| url |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-80051506107&doi=10.1107%2fS1600536811025189&partnerID=40&md5=ad996b41fdf6b277da8cb627fca62cee |
| description |
In the title compound, [Ni(C 15H 13FNO 2) 2], the Ni II atom is tetra-coordinated by two N atoms and two O atoms from two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth- oxy-phenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni II atom are trans to each other, as the Ni II atom lies on an inversion centre. In the fluoro-phenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex molecules are linked via inter-molecular C - H⋯F hydrogen bonds, forming chains along [001]. |
| publisher |
|
| issn |
16005368 |
| language |
English |
| format |
Article |
| accesstype |
All Open Access; Gold Open Access; Green Open Access |
| record_format |
scopus |
| collection |
Scopus |
| _version_ |
1820775481099681792 |