Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato- κ 2 N,O 1}nickel(II)
In the title compound, [Ni(C 15H 13FNO 2) 2], the Ni II atom is tetra-coordinated by two N atoms and two O atoms from two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth- oxy-phenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni II atom are trans to each other, as t...
| Published in: | Acta Crystallographica Section E: Structure Reports Online |
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| Main Author: | |
| Format: | Article |
| Language: | English |
| Published: |
2011
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-80051506107&doi=10.1107%2fS1600536811025189&partnerID=40&md5=ad996b41fdf6b277da8cb627fca62cee |
| Summary: | In the title compound, [Ni(C 15H 13FNO 2) 2], the Ni II atom is tetra-coordinated by two N atoms and two O atoms from two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth- oxy-phenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni II atom are trans to each other, as the Ni II atom lies on an inversion centre. In the fluoro-phenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex molecules are linked via inter-molecular C - H⋯F hydrogen bonds, forming chains along [001]. |
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| ISSN: | 16005368 |
| DOI: | 10.1107/S1600536811025189 |